Control of the sign of exchange interactions in solvent-separated radical ion pairs

被引：2
|
作者：
Tero-Kubota, S [1 ]
Zikihara, K
Yago, T
Kobori, Y
Akiyama, K
机构：
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
[2] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
来源：
APPLIED MAGNETIC RESONANCE | 2004年 / 26卷 / 1-2期
关键词：
D O I：
10.1007/BF03166568
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The chemically induced dynamic electron polarization spectra generated by the laser photolysis of several donor-acceptor systems have been studied to verify the solvent effects on the exchange interaction in solvent-separated radical ion pairs. It has been shown that the sign of the exchange interaction depends on the polarity of solvents. The individual reorganization energies have been determined for several solvent-separated radical ion pair systems.
引用
收藏
页码：145 / 154
页数：10
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