A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties

被引：36
作者：
Rinfray, Corentin [1 ]
Renaudineau, Severine [1 ]
Izzet, Guillaume [1 ]
Proust, Anna [1 ]
机构：
[1] Univ Paris 06, Sorbonne Univ, CNRS, Inst Parisien Chim Mol,UMR 8232, F-75252 Paris 05, France
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 62期
关键词：
POLYOXOMETALATES SYNTHESIS; POST-FUNCTIONALIZATION; KEGGIN; POLYOXOTUNGSTATES; DERIVATIVES; PLATFORMS; RUTHENIUM; CHEMISTRY; POLYMERS; CLUSTERS;
D O I：
10.1039/c4cc03779k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new polyoxomolybdate-based hybrid platform TBA(4)[PMo11O39-{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.
引用
收藏
页码：8575 / 8577
页数：3
相关论文
共 31 条
  • [11] Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems
    Hill, CL
    [J]. CHEMICAL REVIEWS, 1998, 98 (01) : 1 - 2
  • [12] Cyclodextrin-Induced Auto-Healing of Hybrid Polyoxometalates
    Izzet, Guillaume
    Menand, Mickael
    Matt, Benjamin
    Renaudineau, Severine
    Chamoreau, Lise-Marie
    Sollogoub, Matthieu
    Proust, Anna
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (02) : 487 - 490
  • [13] Nanohybridization of Polyoxometalate Clusters and Single-Wall Carbon Nanotubes: Applications in Molecular Cluster Batteries
    Kawasaki, Naoya
    Wang, Heng
    Nakanishi, Ryo
    Hamanaka, Shun
    Kitaura, Ryo
    Shinohara, Hisanori
    Yokoyama, Toshihiko
    Yoshikawa, Hirofumi
    Awaga, Kunio
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (15) : 3471 - 3474
  • [14] Polyoxometalate-based functional nanostructured films: Current progress and future prospects
    Liu, Shaoqin
    Tang, Zhiyong
    [J]. NANO TODAY, 2010, 5 (04) : 267 - 281
  • [15] Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
    Long, De-Liang
    Burkholder, Eric
    Cronin, Leroy
    [J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) : 105 - 121
  • [16] Versatile Post-functionalization of Polyoxometalate Platforms By Using An Unprecedented Range of Palladium-Catalyzed Coupling Reactions
    Lorion, Melanie M.
    Matt, Benjamin
    Alves, Sandra
    Proust, Anna
    Poli, Giovanni
    Oble, Julie
    Izzet, Guillaume
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (38) : 12607 - 12612
  • [17] A VOLTAMMETRIC STUDY OF KEGGIN-TYPE HETEROPOLYMOLYBDATE ANIONS
    MAEDA, K
    HIMENO, S
    OSAKAI, T
    SAITO, A
    HORI, T
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 364 (1-2): : 149 - 154
  • [18] Hybrid Polyoxometalates: Keggin and Dawson Silyl Derivatives as Versatile Platforms
    Matt, B.
    Renaudineau, S.
    Chamoreau, L. -M.
    Afonso, C.
    Izzet, G.
    Proust, A.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (09) : 3107 - 3112
  • [19] Long lived charge separation in iridium(III)-photosensitized polyoxometalates: synthesis, photophysical and computational studies of organometallic-redox tunable oxide assemblies
    Matt, Benjamin
    Xiang, Xu
    Kaledin, Alexey L.
    Han, Nannan
    Moussa, Jamal
    Amouri, Hani
    Alves, Sandra
    Hill, Craig L.
    Lian, Tianquan
    Musaev, Djamaladdin G.
    Izzet, Guillaume
    Proust, Anna
    [J]. CHEMICAL SCIENCE, 2013, 4 (04) : 1737 - 1745
  • [20] Elegant Approach to the Synthesis of a Unique Heteroleptic Cyclometalated Iridium(III)-Polyoxometalate Conjugate
    Matt, Benjamin
    Moussa, Jamal
    Chamoreau, Lise-Marie
    Afonso, Carlos
    Proust, Anna
    Amouri, Hani
    Izzet, Guillaume
    [J]. ORGANOMETALLICS, 2012, 31 (01) : 35 - 38
1234