A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties

被引：36
作者：
Rinfray, Corentin [1 ]
Renaudineau, Severine [1 ]
Izzet, Guillaume [1 ]
Proust, Anna [1 ]
机构：
[1] Univ Paris 06, Sorbonne Univ, CNRS, Inst Parisien Chim Mol,UMR 8232, F-75252 Paris 05, France
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 62期
关键词：
POLYOXOMETALATES SYNTHESIS; POST-FUNCTIONALIZATION; KEGGIN; POLYOXOTUNGSTATES; DERIVATIVES; PLATFORMS; RUTHENIUM; CHEMISTRY; POLYMERS; CLUSTERS;
D O I：
10.1039/c4cc03779k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new polyoxomolybdate-based hybrid platform TBA(4)[PMo11O39-{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.
引用
收藏
页码：8575 / 8577
页数：3
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