Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C-H activation

被引：157
作者：
Zheng, Guangfan [1 ]
Tian, Miaomiao [2 ]
Xu, Youwei [1 ]
Chen, Xiaohong [1 ]
Li, Xingwei [1 ,2 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 06期
关键词：
ALPHA-DIAZO ESTERS; N BOND FORMATION; CARBENOID FUNCTIONALIZATION; OXIDATIVE ANNULATION; BETA-PHENYLETHYLAMINES; ISOQUINOLINE ALKALOIDS; RHODIUM CATALYSIS; GENERAL-METHOD; ALKYNES; SULFOXIMINES;
D O I：
10.1039/c7qo01033h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Rh(iii)-catalyzed annulative C-H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.
引用
收藏
页码：998 / 1002
页数：5
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