Inert effects on the flammability characteristics of methanol by nitrogen or carbon dioxide

被引:6
作者
Chiang, C. -C. [2 ,3 ]
Lee, J. -C. [1 ]
Chang, Y. -M. [1 ]
Chuang, C. -F.
Shu, C. -M. [1 ]
机构
[1] Natl Yunlin Univ Sci & Technol, Grad Sch Engn Sci & Technol, Doctoral Program, Touliu, Yunlin, Taiwan
[2] Natl Changhua Univ Educ, Doctoral Program, Dept Ind Educ & Technol, Changhua 50074, Taiwan
[3] Hsiuping Inst Technol, Dept Elect Engn, Taichung 41280, Taiwan
关键词
Flammability characteristics; Flammable chemicals; Inert component; 20-L-Apparatus; Methanol; GAS-MIXTURES; CUMENE HYDROPEROXIDE; HAZARD EVALUATION; ACETONE;
D O I
10.1007/s10973-009-0028-1
中图分类号
O414.1 [热力学];
学科分类号
摘要
Knowledge of material safety properties is critical for safe handing in the chemical process industries, especially for flammable chemicals that might result in serious fires and explosions. This study investigated the flammability characteristics of methanol under working conditions during the process. The targeted fire and explosion properties, like explosion limits (UEL and LEL), vapor deflagration index (K (g)), maximum explosion pressure (P (max)), and maximum explosion pressure rise [(dP dt (-1))(max)], were deliberately obtained via a 20-L-Apparatus in 101 kPa (i.e., 760 mmHg/1 atm), 150 and 200 A degrees C, along with various experimental arrangements containing nitrogen (N-2) or carbon dioxide (CO2) as inert component. Particularly, this study discussed and elucidated the inert influence on the above safety-related parameters by two different inerting gases of N-2 and CO2. The results indicated that adding an inert component to fuel-inert gas mixtures determined the decrease of explosion range and flammability hazard degree. The results also demonstrated that CO2 possessed higher inerting capability than N-2 in this study.
引用
收藏
页码:759 / 763
页数:5
相关论文
共 29 条
[1]  
[Anonymous], E68104 ASTM
[2]  
[Anonymous], 2002, 68 NFPA
[3]  
*ASTM, 1992, E91883 ASTM
[4]  
*ASTM, 1991, E68185 ASTM
[5]   Flammability envelopes for methanol, ethanol, acetonitrile and toluene [J].
Brooks, Mark R. ;
Crowl, Daniel A. .
JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES, 2007, 20 (02) :144-150
[6]   Thermal hazard evaluation of carbon nanotubes with sulfuric acid by DSC [J].
Chang, C. -W. ;
Chou, Y. -C. ;
Tseng, J. -M. ;
Liu, M. -Y. ;
Shu, C. -M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (02) :639-643
[7]  
CHANG WH, 1994, METHANOL PRODUCTION, V57
[8]   Flammability characteristics studies on toluene and methanol mixtures with different vapor mixing ratios at 1 atm and 150°C [J].
Chang, Y. M. ;
Lee, J. -C. ;
Chen, J. -R. ;
Liaw, H. -J. ;
Shu, C. -M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 93 (01) :183-188
[9]   Flammability properties analysis of methylphenol-carbonate in diphenylcarbonate production process [J].
Chang, Y. -M. ;
Shu, C. -M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 93 (01) :135-141
[10]   Elevated pressure and temperature effects on flammability hazard assessment for acetone and water solutions [J].
Chang, Y. -M. ;
Lee, J. -C. ;
Wu, S. -Y. ;
Chen, C. -C. ;
Shu, C. -M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (02) :525-534