Pushing the Bounds of Olefin Metathesis with Vanadium

被引：10
作者：
Farrell, Wesley S. [1 ]
机构：
[1] US Naval Acad, Dept Chem, 572 M Holloway Rd, Annapolis, MD 21402 USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2021年 / 647卷 / 06期
关键词：
Vanadium; Olefin Metathesis; High Activity; Earth Abundant Catalysts; Thermal Robustness; RING-OPENING POLYMERIZATION; IMIDO ALKYLIDENE COMPLEXES; RUTHENIUM CATALYSTS; ALPHA-HYDROGEN; THERMALLY ROBUST; CROSS-METATHESIS; FACILE SYNTHESIS; CYCLIC OLEFINS; LIVING ROMP; MOLYBDENUM;
D O I：
10.1002/zaac.202000403
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Olefin metathesis has been a key player in organic and polymer synthesis for over 50 years. While countless catalysts have been reported over this time, new compounds that offer improved selectivity, efficiency, robustness, and/or cost-effectiveness are still highly desired. This minireview will detail efforts made in this regard through the development of catalysts based on abundant and inexpensive vanadium. Special attention will be given to reports within the past three years concerning ring-opening metathesis polymerization of low ring-strain cyclic olefins and expansion to other olefin metathesis transformations, such as cross-metathesis.
引用
收藏
页码：584 / 592
页数：9
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