A Clean Process for Obtaining High-Quality Cellulose Acetate from Cigarette Butts

被引:41
作者
De Fenzo, Anna [1 ]
Giordano, Michele [2 ]
Sansone, Lucia [2 ]
机构
[1] Univ Napoli Federico II, Dept Chem Mat & Prod Engn DICMAPI, Pzzale Tecchio 80, I-80125 Naples, Italy
[2] Natl Res Council Italy CNR, Inst Polymers Composites & Biomat, I-80055 Portici, Italy
关键词
cigarette butts; cellulose acetate; extraction process; recovery; THERMAL-DEGRADATION; KINETIC-ANALYSIS; ACTIVATION; ENERGY; SUBSTITUTION; POLLUTANTS; TOXICITY; MODEL;
D O I
10.3390/ma13214710
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The main purpose of this study is to introduce a modified method for recovering and recycling huge number of cigarette butts (CBs) and convert them into a fashion product. CBs are non-biodegradable waste, generally, discarded improperly into the environment. CBs consist of cellulose acetate, which can be recovered through extraction and purification processes. CBs are the most numerically frequent form of waste in the world. A relevant portion of CBS are discarded improperly into the environment. The principal filter components are plasticized cellulose acetate fibers that have the slowest degradation rate (up to years). In fact, a limiting step is the hydrolysis of cellulose acetate polymer into cellulose and acetic acid, which is extremely slow under ambient conditions and represents a relevant environmental risk. A number of studies have been realized on recycling cigarette butts with encouraging results, and several methods have been studied, including recycling of cigarette butts in asphalt concrete and fired clay bricks, as a carbon source, sound-absorbing material, corrosion inhibitor, biofilm carrier, and many more. In this study, we propose a novel, green, low cost, simple, and efficient extraction method of cellulose acetate fibers (CA) from discarded cigarette butts (DCBs). CBs extraction procedure involves a two-step process consisting of washings in water and some subsequent washings in ethanol. The obtained samples of CA are dried at 60 degrees C for 60 min in the oven. The quality and properties of cellulose acetate extracted and purified are comparable to the pure cellulose acetate fiber used for cigarette butts. The preliminary results obtained on the recovered CA look promising to the use of this recovery material from cigarette butts to obtain a wide consumption fashion product, such as eyeglass frames.
引用
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页码:1 / 13
页数:13
相关论文
共 35 条
[1]   Model fitting kinetic analysis and characterisation of the devolatilization of coal blends with corn and sugarcane residues [J].
Aboyade, Akinwale O. ;
Carrier, Marion ;
Meyer, Edson L. ;
Knoetze, Johannes H. ;
Goergens, Johann F. .
THERMOCHIMICA ACTA, 2012, 530 :95-106
[2]   Facile functionalization of cellulose from discarded cigarette butts for the removal of diclofenac from water [J].
Abu-Danso, Emmanuel ;
Bagheri, Afrouz ;
Bhatnagar, Amit .
CARBOHYDRATE POLYMERS, 2019, 219 :46-55
[3]  
[Anonymous], 2005, E69805 ASTM INT
[4]  
Browne C.L., 1990, The Design of Cigarettes, V3rd
[5]   Process development for cigarette butts recycling into cellulose pulp [J].
d'Heni Teixeira, Maria Betania ;
Duarte, Marco Antonio B. ;
Garcez, Loureine Raposo ;
Rubim, Joel Camargo ;
Gatti, Therese Hofmann ;
Ziani Suarez, Paulo Anselmo .
WASTE MANAGEMENT, 2017, 60 :140-150
[6]   Desorption corona beam ionisation (DCBI) mass spectrometry for in-situ analysis of adsorbed phenol in cigarette acetate fiber filter [J].
Du, Wen ;
Tang, Li-Juan ;
Wen, Jian-Hui ;
Zhong, Ke-Jun ;
Jiang, Jian-Hui ;
Wang, Hua ;
Chen, Bo ;
Yu, Ru-Qin .
TALANTA, 2015, 131 :499-504
[7]   Quantitative analysis of cellulose acetate with a high degree of substitution by FTIR and its application [J].
Fei, Pengfei ;
Liao, Liang ;
Cheng, Bowen ;
Song, Jun .
ANALYTICAL METHODS, 2017, 9 (43) :6194-6201
[8]   THE ISOCONVERSIONAL METHOD FOR DETERMINATION OF ENERGY OF ACTIVATION AT CONSTANT HEATING RATES - CORRECTIONS FOR THE DOYLE APPROXIMATION [J].
FLYNN, JH .
JOURNAL OF THERMAL ANALYSIS, 1983, 27 (01) :95-102
[9]   A GENERAL DIFFERENTIAL TECHNIQUE FOR THE DETERMINATION OF PARAMETERS FOR D(ALPHA)/DT = F(ALPHA)A EXP (-E/RT) - ENERGY OF ACTIVATION, PREEXPONENTIAL FACTOR AND ORDER OF REACTION (WHEN APPLICABLE) [J].
FLYNN, JH .
JOURNAL OF THERMAL ANALYSIS, 1991, 37 (02) :293-305
[10]  
Ghosh TK, 2017, J INDIAN CHEM SOC, V94, P863