NanoTafla Nanocomposite as a Novel Low-Cost and Eco-Friendly Sorbent for Strontium and Europium Ions

被引:11
作者
Abu Elgoud, Elsayed M. [1 ]
Aly, Mohamed, I [1 ]
Hamed, Mostafa M. [1 ]
Nayl, AbdElAziz A. [2 ]
机构
[1] Egyptian Atom Energy Author, Hot Labs & Waste Management Ctr, Cairo 13759, Egypt
[2] Jouf Univ, Coll Sci, Dept Chem, Sakaka 42421, Aljouf, Saudi Arabia
关键词
AQUEOUS-SOLUTIONS; EFFICIENT REMOVAL; HUMIC-ACID; CORE-SHELL; ADSORPTION; EU(III); SR(II); U(VI); MONTMORILLONITE; ACTINIDES;
D O I
10.1021/acsomega.1c07255
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Now the wide use of nanooxides is attributed to their remarkable collection of properties. Nanocomposites have an impressive variety of important applications. A thermal decomposition approach provides a more optimistic method for nanocrystal synthesis due to the low cost, high efficiency, and expectations for large-scale production. Therefore, in this study a new eco-friendly nanooxide composite with sorption characteristics for europium (Eu(III)) and strontium (Sr(II)) was synthesized by a one-step thermal treatment process using earth-abundant tafla clay as a starting material to prepare a modified tafla (M-Taf) nanocomposite. The synthesized nancomposite was characterized by different techniques before and after sorption processes. Different factors that affected the sorption behavior of Eu(III) and Sr(II) in aqueous media by the M-Taf nanocomposite were studied. The results obtained illustrated that the kinetics of sorption of Eu(III) and Sr(II) by the M-Taf nanocomposite are obeyed according to the pseudo-second order and controlled by a Langmuir isotherm model with maximum sorption capacities (Qmax) of 25.5 and 23.36 mg/g for Eu(III) and Sr(II), respectively. Also, this novel low-cost and eco-friendly sorbent has promising properties and can be used to separate and retain some radionuclides in different applications.
引用
收藏
页码:10447 / 10457
页数:11
相关论文
共 72 条
[1]   Enhancing the removal of organic and inorganic selenium ions using an exfoliated kaolinite/cellulose fibres nanocomposite [J].
Abukhadra, Mostafa R. ;
AlHammadi, Ali ;
El-Sherbeeny, Ahmed M. ;
Salam, Mohamed Abdel ;
El-Meligy, Mohammed A. ;
Awwad, Emad Mahrous ;
Luqman, Monis .
CARBOHYDRATE POLYMERS, 2021, 252
[2]   The effect of thermal and acid treatment of kaolin on its ability for cyanide removal from aqueous solutions [J].
Behnamfard, Ali ;
Chegni, Kamran ;
Alaei, Rasool ;
Veglio, Francesco .
ENVIRONMENTAL EARTH SCIENCES, 2019, 78 (14)
[3]   Surface complexation modeling of Sr(II) and Eu(III) adsorption onto oxidized multiwall carbon nanotubes [J].
Chen, Changlun ;
Hu, Jun ;
Xu, Di ;
Tan, Xiaoli ;
Meng, Yuedong ;
Wang, Xiangke .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 323 (01) :33-41
[4]   Eu(III) uptake on rectorite in the presence of humic acid: A macroscopic and spectroscopic study [J].
Chen, Changlun ;
Yang, Xin ;
Wei, Juan ;
Tan, Xiaoli ;
Wang, Xiangke .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2013, 393 :249-256
[5]   Iron/Carbon Composites for Cr(VI) Removal Prepared from Harmful Algal Bloom Biomass via Metal Bioaccumulation or Biosorption [J].
Cui, Yanbin ;
He, Haoxin ;
Atkinson, John D. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (01) :1279-1288
[6]   Extraction of lanthanides and actinides present in spent nuclear fuel and in electronic waste [J].
De Jesus, Karl ;
Rodriguez, Rene ;
Baek, D. L. ;
Fox, R., V ;
Pashikanti, Srinath ;
Sharma, Kavita .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 336 (336)
[7]   Adsorption of chromium (VI) and iron (III) ions onto acid-modified kaolinite: Isotherm, kinetics and thermodynamics studies [J].
Dim, P. E. ;
Mustapha, L. S. ;
Termtanun, M. ;
Okafor, J. O. .
ARABIAN JOURNAL OF CHEMISTRY, 2021, 14 (04)
[8]   Adsorption of humic acid and Eu(III) to multi-walled carbon nanotubes: Effect of pH, ionic strength and counterion effect [J].
Fan, Q. H. ;
Shao, D. D. ;
Hu, J. ;
Chen, C. L. ;
Wu, W. S. ;
Wang, X. K. .
RADIOCHIMICA ACTA, 2009, 97 (03) :141-148
[9]   Facile solid-state synthesis of Fe3O4/kaolinite nanocomposites for enhanced dye adsorption [J].
Fei, F. ;
Gao, Z. ;
Wu, H. ;
Wurendaodi, W. ;
Zhao, S. ;
Asuha, S. .
JOURNAL OF SOLID STATE CHEMISTRY, 2020, 291
[10]   Design and synthesis of self-assembled monolayers on mesoporous supports (SAMMS): The importance of ligand posture in functional nanomaterials [J].
Fryxell, Glen E. ;
Mattigod, Shas V. ;
Lin, Yuehe ;
Wu, Hong ;
Fiskum, Sandy ;
Parker, Kent ;
Zheng, Feng ;
Yantasee, Wassana ;
Zemanian, Tom S. ;
Addleman, R. Shane ;
Liu, Jun ;
Kemner, Ken ;
Kelly, Shelly ;
Feng, Xiangdong .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (28) :2863-2874