The behaviour of cellulose in hydrated melts of the composition LiX•nH2O (X = I-, NO3-, CH3COO-, ClO4-)

被引：90
作者：
Fischer, S
Voigt, W
Fischer, K
机构：
[1] TEch Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
[2] Tech Univ Dresden, Inst Pflanzen & Holzchem, D-01737 Tharandt, Germany
来源：
CELLULOSE | 1999年 / 6卷 / 03期
关键词：
low temperature molten salts; cellulose solvents; X-ray scattering; molecular weight distribution;
D O I：
10.1023/A:1009269614096
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
The dissolution behaviour of cellulose in low temperature molten salts was investigated. Depending on the chosen anions in the melt, cellulose shows different reaction behaviour in different Li+-containing melts. Dissolution of the polymer was observed in molten LiClO4. 3H(2)O and molten LiI . 2H(2)O. In the hydrated melts of LiCH3COO . 2H(2)O and LiNO3. 3H(2)O a fine distribution of cellulose was stated. Cellulose can be regenerated by cooling the melt and removing the salt by dissolution in water. The structure of the recrystallized product is determined by the used low temperature molten salt.
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页码：213 / 219
页数：7
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