A facile hydrothermal route to spinel CoCo2O4 nanotubes and porous nanostructures without assisted surfactants and templates

被引:11
作者
Song, Limin [2 ]
Zhang, Shujuan [1 ]
Chen, Bin [2 ]
Zhang, Shuna [3 ]
Sun, Donglan [1 ]
机构
[1] Tianjin Univ Sci & Technol, Coll Sci, Tianjin 300457, Peoples R China
[2] Tianjin Polytech Univ, Coll Mat Sci & Chem Engn, Tianjin 300160, Peoples R China
[3] Zhejiang Ind Polytech Coll, Shaoxing 312000, Peoples R China
关键词
CoCo2O4; nanostructures; Hydrothermal; Electrochemical properties; CO3O4; BATTERY;
D O I
10.1016/j.matlet.2009.01.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Spinel CoCo2O4 nanotubes and porous nanostructures have been synthesized by a novel hydrothermal method from Co(NO3)(2)center dot 6H(2)O in mixtures of ammonia and cyclohexane at 220 degrees C. The morphology and phase of CoCo2O4 can be controlled by adjusting the experimental parameters that include the Co2+ concentration and the volume ratio of ammonia to cyclohexane. X-ray diffraction and transmission electron microscopy analyses were used to characterize the products. The formation mechanisms of CoCo2O4 nanostructures is proposed in detail. The electrochemical properties of the as-prepared samples have been investigated. (C) 2009 Published by Elsevier B.V.
引用
收藏
页码:1377 / 1380
页数:4
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