Effect of nano-TiO2 on the physical, mechanical and optical properties of pullulan film

被引:83
作者
Liu, Yaofa [1 ]
Liu, Yuanyuan [1 ]
Han, Ke [1 ]
Cai, Ying [1 ]
Ma, Meihu [1 ]
Tong, Qunyi [2 ]
Sheng, Long [1 ]
机构
[1] Huazhong Agr Univ, Coll Food Sci & Technol, Natl Res & Dev Ctr Egg Proc, Wuhan 430070, Hubei, Peoples R China
[2] Jiangnan Univ, Sch Food Sci & Technol, State Key Lab Food Sci & Technol, Wuxi, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Polysaccharide film; Nano-TiO2; Pullulan; Nanocomposite; NANOCOMPOSITE FILMS; EDIBLE FILMS; ANTIBACTERIAL ACTIVITY; BIODEGRADABLE FILMS; TIO2; NANOPARTICLES; BARRIER PROPERTIES; PROTEIN; FERMENTATION; GELLAN;
D O I
10.1016/j.carbpol.2019.04.073
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, effects of nano-TiO2 on the microstructural, physical, mechanical and optical properties of pullulan films were investigated. The results showed that the addition of nano-TiO2 improved the water vapor barrier properties of the film due to the tortuous path formed by nano-TiO2. When the concentration of nano-TiO2 was 0.04 g/100 mL, the tensile strength of the film showed a maximum value (15.99 MPa). The elongation at break of the film continued to decrease with the increase of nano-TiO2 The TEM analysis showed that higher concentration of nano-TiO2 would cause greater aggregation. Meanwhile, the results of FTIR and low-field NMR indicated that the miscibility between pullulan and nano-TiO2 was due to the formation of intermolecular hydrogen bonds during film formation. Furthermore, the addition of nano-TiO2 significantly improved the film barrier properties to ultraviolet light.
引用
收藏
页码:95 / 102
页数:8
相关论文
共 50 条
[1]  
[Anonymous], 2002, ASTM D882-02 Standard test method for tensile properties of thin plastic sheeting
[2]   Review: Nanocomposites in Food Packaging [J].
Arora, Amit ;
Padua, G. W. .
JOURNAL OF FOOD SCIENCE, 2010, 75 (01) :R43-R49
[3]  
ASTM E., 1993, STAND TEST METH WAT
[4]   Influence of colloidal silica nanoparticles on pullulan-coated BOPP film [J].
Cozzolino, Carlo A. ;
Castelli, Giulia ;
Trabattoni, Silvia ;
Farris, Stefano .
FOOD PACKAGING AND SHELF LIFE, 2016, 8 :50-55
[5]   Pullulan- Based Films and Coatings for Food Packaging: Present Applications, Emerging Opportunities, and Future Challenges [J].
Farris, Stefano ;
Unalan, Ilke Uysal ;
Introzzi, Laura ;
Maria Fuentes-Alventosa, Jose ;
Cozzolino, Carlo A. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (13)
[6]   Preparation and characterization of novel nanocomposite films formed from silk fibroin and nano-TiO2 [J].
Feng, Xin-Xing ;
Zhang, Li-Li ;
Chen, Jian-Yong ;
Guo, Yu-Hai ;
Zhang, Hua-Peng ;
Jia, Chang-Ian .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2007, 40 (02) :105-111
[7]   Functional properties of soy protein isolate edible films as affected by rapeseed oil concentration [J].
Galus, Sabina .
FOOD HYDROCOLLOIDS, 2018, 85 :233-241
[8]   Development of active rosmarinic acid-gelatin biodegradable films with antioxidant and long-term antibacterial activities [J].
Ge, Liming ;
Zhu, Mingjin ;
Li, Xinying ;
Xu, Yongbin ;
Ma, Xiaonan ;
Shi, Rong ;
Li, Defu ;
Mu, Changdao .
FOOD HYDROCOLLOIDS, 2018, 83 :308-316
[9]   New insights into the aquatic photochemistry of fluoroquinolone antibiotics: Direct photodegradation, hydroxyl-radical oxidation, and antibacterial activity changes [J].
Ge, Linke ;
Na, Guangshui ;
Zhang, Siyu ;
Li, Kai ;
Zhang, Peng ;
Ren, Honglei ;
Yao, Ziwei .
SCIENCE OF THE TOTAL ENVIRONMENT, 2015, 527 :12-17
[10]   Mechanical and barrier properties of egg albumen films [J].
Gennadios, A ;
Weller, CL ;
Hanna, MA ;
Froning, GW .
JOURNAL OF FOOD SCIENCE, 1996, 61 (03) :585-589