Self- assembly of a luminescent Zn( II) carboxylate with the diamondoid topology

被引：4
|
作者：
Zhang, Tian [1 ]
Wang, Gui-Xia [1 ]
Xue, Li-ping [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2014年 / 49卷 / 04期
关键词：
Zn(II) coordination polymer; crystal structure; diamondoid topology; photoluminescent property; CRYSTAL-STRUCTURES; COORDINATION; INTERPENETRATION; SORPTION;
D O I：
10.1002/crat.201300394
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new coordination polymer [Zn(tdc)(bimb)]n(1) ( H2tdc = 3,4-thiophenedicarboxylic acid, bimb = 1,4- bis(imidazol-1'yl) butane) has been synthesized under hydrothermal condition. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the space group P212121 of orthorhombic crystal system: a = 10.517( 2), b = 10.889( 2), c = 15.206( 3) angstrom. This compound features a 3D network which can be rationalized as a 4- connected diamondoid net. Moreover, thermal and photoluminescent properties for 1 have also been investigated.
引用
收藏
页码：257 / 261
页数：5
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