Polyoxometalates: Fascinating structures, unique magnetic properties

被引：522

作者：

Kortz, Ulrich ^{[1
]}

Mueller, Achim ^{[2
]}

van Slageren, Joris ^{[3
,4
]}

Schnack, Juergen ^{[5
]}

Dalal, Naresh S. ^{[6
,7
]}

Dressel, Martin ^{[3
]}

机构：

[1] Jacobs Univ, Sch Engn & Sci, D-28725 Bremen, Germany

[2] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

[3] Univ Stuttgart, Inst Phys 1, D-70550 Stuttgart, Germany

[4] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[5] Univ Bielefeld, Fak Phys, D-33501 Bielefeld, Germany

[6] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[7] Natl High Magnet Field Lab, Tallahassee, FL 32306 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 19-20期

基金：

美国国家科学基金会;

关键词：

Polyoxometalates; Transition metals; Lanthanides; Magnetism; Electron spin resonance; SINGLE-MOLECULE MAGNETS; PENTANUCLEAR COPPER(II) COMPLEXES; ANISOTROPIC EXCHANGE INTERACTIONS; INELASTIC NEUTRON-SCATTERING; NUCLEARITY SPIN CLUSTERS; ANTISYMMETRIC EXCHANGE; X-RAY; CONFINED CONDITIONS; NUCLEATION PROCESS; CRYSTAL-STRUCTURE;

D O I：

10.1016/j.ccr.2009.01.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report on several discrete molecular transition metal- and lanthanide-containing polyoxo-tungstates and -molybdates with a focus on their magnetic properties. The polyanions discus sed here all contain 3d paramagnetic centers and are mostly of the spherical {Mo-132} Keplerate type, the cyclic {P8W48} type, the dimeric {(X2W18)-W-III} (X = As, Sb) type, and the dimeric, fused {Si2W18} type. The number of incorporated magnetic ions in the structures described here ranges from 3 to 30. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2315 / 2327

页数：13

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