Assembly of Cerium(III) 2,2′-Bipyridine-5,5′-dicarboxylate-based Metal-Organic Frameworks by Solvent Tuning

被引：22

作者：

Ayhan, Ozan ^{[1
]}

Malaestean, Iurie L. ^{[1
]}

Ellern, Arkady ^{[2
]}

van Leusen, Jan ^{[1
]}

Baca, Svetlana G. ^{[1
,3
]}

Koegerler, Paul ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany

[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev 2028, Moldova

来源：

CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 07期

关键词：

STRUCTURAL-CHARACTERIZATION; HYDROTHERMAL SYNTHESIS; COORDINATION; CRYSTAL;

D O I：

10.1021/cg500815v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Small changes to the reaction conditions differentiate between two metal organic frameworks (MOFs), {[Ce-2(H2O)(bpdc)(3)(dmf)(2)]center dot 2(dmf)}(n) (1) and {[Ce-4(H2O)(5)(bpdc)(6)(dmf)]center dot x(dmf)}(n) (2), that were solvothermally synthesized from cerium(III) nitrate hexahydrate and 2,2'-bipyridine-5,5'-dicarboxylic acid (H(2)bpdc) in dimethylformamide (dmf). The two compounds illustrate how the flexibility of the coordination geometry of Ce-III translates into MOFs, the formation of which readily adapts to different solvent environments.

引用

页码：3541 / 3548

页数：8

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