Bis(3-hydroxyphenylacetato-κ2O,O′)bis(1H-imidazole-κN3)nickel(II)

被引:1
作者
Nie, Xiao-Yan [1 ]
Li, Qian-Zhu [1 ]
机构
[1] Bijie Univ, Dept Chem, Bijie 551700, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536809005960
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title mononuclear complex, [Ni(C8H7O3)(2)(C3H4N2)(2)], the Ni-II atom, lying on a twofold rotation axis, is coordinated by four carboxylate O atoms from two bidentate 3-hydroxy-phenylacetato ligands and two N atoms from two imidazole molecules in a distorted octahedral geometry. A three-dimensional network is formed via intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds and pi-pi stacking interactions between the imidazole and benzene rings of neighboring molecules [centroid-centroid distance = 3.856 (2) angstrom].
引用
收藏
页码:M330 / U888
页数:9
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