Substrate effects on photophysical properties of fluorescent self-assembled monolayers (SAMs)

被引:3
作者
Jadhav, Sushilkumar A. [1 ,2 ]
机构
[1] Univ Torino, Dept Chem, Via P Giuria 7, I-10125 Turin, Piedmont, Italy
[2] Univ Torino, NIS Res Ctr, Via P Giuria 7, I-10125 Turin, Piedmont, Italy
关键词
self-assembled monolayers (SAMs); fluorescent SAMs; substrate-fluorophore interactions; fluorescence quenching; fluorescence enhancement; PYRENE EXCIMER FLUORESCENCE; GOLD NANOPARTICLES; ENHANCED FLUORESCENCE; FILM SENSOR; MOLECULAR FLUORESCENCE; BUILDING-BLOCKS; SURFACE; SPECTROSCOPY; DERIVATIVES; CARBAZOLE;
D O I
10.1002/poc.3611
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Substrate materials play an important role to modulate the photophysical properties of fluorescent self-assembled monolayers (SAMs) constructed on them. The substrate-fluorophore interactions in fluorescent SAMs can affect their fluorescence intensity. Hence, it is important to take into account such alteration of fluorescence properties and study the underlying mechanisms. In this brief overview, substrate effects on fluorescence properties of chemisorbed or physisorbed fluorescent SAMs on two-dimensional (chips) and three-dimensional (nanoparticles) surfaces are highlighted. Examples of fluorescence quenching and enhancement on various substrate materials by different factors are discussed and analyzed. Additionally, some strategies to limit metallic substrate-fluorophore interactions are discussed briefly. Copyright (c) 2016 John Wiley & Sons, Ltd.
引用
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页数:9
相关论文
共 64 条
[1]   THE UV-VISIBLE ABSORPTION AND FLUORESCENCE OF SOME SUBSTITUTED 1,8-NAPHTHALIMIDES AND NAPHTHALIC ANHYDRIDES [J].
ALEXIOU, MS ;
TYCHOPOULOS, V ;
GHORBANIAN, S ;
TYMAN, JHP ;
BROWN, RG ;
BRITTAIN, PI .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (05) :837-842
[2]   The Extent of Pyrene Excimer Fluorescence Emission Is a Reflector of Distance and Flexibility: Analysis of the Segment Linking the LDL Receptor-Binding and Tetramerization Domains of Apolipoprotein E3 [J].
Bains, Gursharan K. ;
Kim, Sea H. ;
Sorin, Eric J. ;
Narayanaswami, Vasanthy .
BIOCHEMISTRY, 2012, 51 (31) :6207-6219
[3]   Cross-reactive sensor array for metal ion sensing based on fluorescent SAMs [J].
Basabe-Desmonts, Lourdes ;
van der Baan, Frederieke ;
Zimmerman, Rebecca S. ;
Reinhoudt, David N. ;
Crego-Calama, Mercedes .
SENSORS, 2007, 7 (09) :1731-1746
[4]   Design of fluorescent materials for chemical sensing [J].
Basabe-Desmonts, Lourdes ;
Reinhoudt, David N. ;
Crego-Calama, Mercedes .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (06) :993-1017
[5]  
Bespalov V. A., 1992, Journal of Applied Spectroscopy, V56, P478, DOI 10.1007/BF00661748
[6]   EXCIMER FLUORESCENCE SPECTRA OF PYRENE DERIVATIVES [J].
BIRKS, JB ;
CHRISTOPHOROU, LG .
SPECTROCHIMICA ACTA, 1963, 19 (02) :401-410
[7]   Fluorescence lifetime standards for time and frequency domain fluorescence spectroscopy [J].
Boens, Noel ;
Qin, Wenwu ;
Basaric, Nikola ;
Hofkens, Johan ;
Ameloot, Marcel ;
Pouget, Jacques ;
Lefevre, Jean-Pierre ;
Valeur, Bernard ;
Gratton, Enrico ;
vandeVen, Martin ;
Silva, Norberto D., Jr. ;
Engelborghs, Yves ;
Willaert, Katrien ;
Sillen, Alain ;
Rumbles, Garry ;
Phillips, David ;
Visser, Antonie J. W. G. ;
van Hoek, Arie ;
Lakowicz, Joseph R. ;
Malak, Henryk ;
Gryczynski, Ignacy ;
Szabo, Arthur G. ;
Krajcarski, Don T. ;
Tamai, Naoto ;
Miura, Atsushi .
ANALYTICAL CHEMISTRY, 2007, 79 (05) :2137-2149
[8]  
Bunau G. V., 1970, JB BIRKSPHOTOPHYSICS, V74, P1294
[9]   Selective sensing of copper and mercury ions with pyrene-functionalized fluorescent film sensor containing a hydrophilic spacer [J].
Cao, Yuan ;
Ding, Liping ;
Hu, Wenting ;
Wang, Lin ;
Fang, Yu .
APPLIED SURFACE SCIENCE, 2013, 273 :542-548
[10]   Dynamic and static quenching of fluorescence by 1-4 nm diameter gold monolayer-protected clusters [J].
Cheng, PPH ;
Silvester, D ;
Wang, GL ;
Kalyuzhny, G ;
Douglas, A ;
Murray, RW .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (10) :4637-4644