Dioxido-vanadium(V) complex catalyzed oxidation of alcohols and tandem synthesis of oximes: a simple catalytic protocol for C-N bond formation

被引：7

作者：

Kurbah, Sunshine Dominic ^{[1
]}

机构：

[1] Pandit Deendayal Upadhyaya Adarsha Mahavidyalaya, Dept Chem, Eraligool 788723, Assam, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2021年 / 74卷 / 4-6期

关键词：

Oxidation; vanadium(V); oxime; tandem; C-N bond formation; AEROBIC OXIDATION; EFFICIENT;

D O I：

10.1080/00958972.2021.1876230

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis of a vanadium(V) complex characterized by FT-IR and H-1 NMR spectroscopy. The structure of the complex was established by single crystal X-ray crystallography. We also carried out the catalytic oxidation of benzyl alcohol, hetero-aryl alcohols and propargylic alcohols. Tandem synthesis of oximes from alcohols were also carried out using our vanadium(V) complex. The newly synthesized complex acts as a catalyst for oxidation reactions and tandem synthesis of oxime from alcohols. [GRAPHICS] .

引用

页码：905 / 918

页数：14

共 47 条

[1]

[Anonymous], 1996, SHELXL-14, refinements

[2]

[Anonymous], 2004, ANGEW CHEM INT ED, V43

[3]

Arita S., 2008, ANGEW CHEM INT ED EN, V47

[4] Selective oxidation of aromatic primary alcohols to aldehydes using molybdenum acetylide oxo-peroxo complex as catalyst [J].

Biradar, Ankush V. ;

Dongare, Mohan K. ;

Umbarkar, Shubhangi B. .

TETRAHEDRON LETTERS, 2009, 50 (24) :2885-2888

[5]

Bolm C., 2003, COORD CHEM REV, V237

[6] VANADIUM PEROXIDE COMPLEXES [J].

BUTLER, A ;

CLAGUE, MJ ;

MEISTER, GE .

CHEMICAL REVIEWS, 1994, 94 (03) :625-638

[7] Design and synthesis of α,β-unsaturated carbonyl compounds as potential ACE inhibitors [J].

Choo, HYP ;

Peak, KH ;

Park, J ;

Kim, DH ;

Chung, HS .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2000, 35 (06) :643-648

[8] Efficient ruthenium-catalyzed aerobic oxidation of alcohols using a biomimetic coupled catalytic system [J].

Csjernyik, G ;

Éll, AH ;

Fadini, L ;

Pugin, B ;

Bäckvall, JE .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (05) :1657-1662

[9]

da Silva J.A.L., 2011, COORD CHEM REV, V255

[10] Efficient and highly selective oxidation of primary alcohols to aldehydes by N-chlorosuccinimide mediated by oxoammonium salts [J].

Einhorn, J ;

Einhorn, C ;

Ratajczak, F ;

Pierre, JL .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (21) :7452-7454

← 1 2 3 4 5 →