Chiral Zn-salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines

被引：28
|
作者：
Puglisi, Roberta [1 ]
Ballistreri, Francesco P. [1 ]
Gangemi, Chiara M. A. [1 ]
Toscano, Rosa Maria [1 ]
Tomaselli, Gaetano A. [1 ]
Pappalardo, Andrea [1 ,2 ]
Sfrazzetto, Giuseppe Trusso [1 ]
机构：
[1] Univ Catania, Dept Chem Sci, Viale Andrea Doria 6, I-95125 Catania, Italy
[2] INSTM Udr Catania, Viale Andrea Doria 6, I-95125 Catania, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 03期
关键词：
SCHIFF-BASE COMPLEXES; ENANTIOMERIC RECOGNITION; EPOXIDATION; CAVITANDS; CATALYSTS; DERIVATIVES; INDUCTION; OLEFINS; EXCESS; NMR;
D O I：
10.1039/c6nj03592b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of fluorescent chiral Zn-salen hosts, able to efficiently recognise chiral amines via non-covalent interactions, is reported here. The host-guest interactions have been characterised by 2D-NMR spectroscopy in order to elucidate the origin of enantioselectivity.
引用
收藏
页码：911 / 915
页数：5
相关论文
共 50 条
  • [1] Supramolecular Detection of a Nerve Agent Simulant by Fluorescent Zn-Salen Oligomer Receptors
    Puglisi, Roberta
    Mineo, Placido G.
    Pappalardo, Andrea
    Gulino, Antonino
    Sfrazzetto, Giuseppe Trusso
    MOLECULES, 2019, 24 (11):
  • [2] Zn(II) promoted dramatic enhancement in the enantioselective fluorescent recognition of functional chiral amines by a chiral aldehyde
    Huang, Zeng
    Yu, Shanshan
    Wen, Kaili
    Yu, Xiaoqi
    Pu, Lin
    CHEMICAL SCIENCE, 2014, 5 (09) : 3457 - 3462
  • [3] Synthesis and catalytic activity of new macrocyclic chiral salen complexes
    Geon-Joong Kim
    Dae-Woon Park
    Yong-Sug Tak
    Catalysis Letters, 2000, 65 : 127 - 133
  • [4] Synthesis and catalytic activity of new macrocyclic chiral salen complexes
    Kim, GJ
    Park, DW
    Tak, YS
    CATALYSIS LETTERS, 2000, 65 (1-3) : 127 - 133
  • [5] New heterogeneous catalysts for the synthesis of chiral amino acids: Functionalization of organic resins with chiral salen complexes
    Esteves, M. A.
    Gigante, B.
    Santos, C.
    Guerreiro, A. M.
    Baleizao, C.
    CATALYSIS TODAY, 2013, 218 : 65 - 69
  • [6] Exploring the Building-Block Potential of Readily Accessible Chiral [Zn(salen)] Complexes
    Martin, Eddy
    Martinez Belmonte, Marta
    Escudero-Adan, Eduardo C.
    Kleij, Arjan W.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (27) : 4632 - 4641
  • [7] Chiral salen ligands designed to form polymetallic complexes
    Achard, Thierry R. J.
    Clegg, William
    Harrington, Ross W.
    North, Michael
    TETRAHEDRON, 2012, 68 (01) : 133 - 144
  • [8] Synthesis and Conformational Study of a Novel Macrocyclic Chiral(Salen) ligand and its Uranyl and Mn Complexes
    Amato, Maria E.
    Ballistreri, Francesco P.
    Pappalardo, Andrea
    Tomaselli, Gaetano A.
    Toscano, Rosa M.
    MOLECULES, 2010, 15 (03): : 1442 - 1452
  • [9] Application of Mesoporous Silica Foam for Immobilization of Salen Complexes in Chiral Intermediates Synthesis
    Jeon, Hoon-Gi
    Choi, Seong Dae
    Jeon, Sang Kwon
    Park, Geun Woo
    Yang, Jin Young
    Kim, Geon-Joong
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2015, 36 (05) : 1396 - 1404
  • [10] Recent Advances in Chiral Catalysis Using Metal Salen Complexes
    Shiryaev, Andrey K.
    CURRENT ORGANIC CHEMISTRY, 2012, 16 (15) : 1788 - 1807
12345