Post-synthetic pore-space expansion in a di-tagged metal-organic framework

被引：15

作者：

Tshering, Lodey ^{[1
]}

Hunter, Sally O. ^{[1
]}

Nikolich, Alexandra ^{[1
]}

Minato, Erica ^{[1
]}

Fitchett, Christopher M. ^{[2
]}

D'Alessandro, Deanna M. ^{[3
]}

Richardson, Christopher ^{[1
]}

机构：

[1] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

[2] Univ Canterbury, Dept Chem, Coll Sci, Christchurch 1, New Zealand

[3] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 39期

关键词：

CARBON-DIOXIDE CAPTURE; POSTSYNTHETIC MODIFICATION; FUNCTIONAL-GROUPS; ADSORPTION; CLICK; TOOL; CO2;

D O I：

10.1039/c4ce01377h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rarely observed example of post-synthetically increasing pore space, while retaining the chemical functionality of the original metal-organic framework is reported. Conventional solvothermal heating in air was used to effect an efficient post-synthetic rearrangement of a bisallyloxy-tagged zinc metal-organic framework. This leads to the pore-space expanded MOF displaying a higher surface area yet lower affinity for CO2 sorption compared to the original MOF.

引用

页码：9158 / 9162

页数：5

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