Post-synthetic pore-space expansion in a di-tagged metal-organic framework

被引：15

作者：

Tshering, Lodey ^{[1
]}

Hunter, Sally O. ^{[1
]}

Nikolich, Alexandra ^{[1
]}

Minato, Erica ^{[1
]}

Fitchett, Christopher M. ^{[2
]}

D'Alessandro, Deanna M. ^{[3
]}

Richardson, Christopher ^{[1
]}

机构：

[1] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

[2] Univ Canterbury, Dept Chem, Coll Sci, Christchurch 1, New Zealand

[3] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 39期

关键词：

CARBON-DIOXIDE CAPTURE; POSTSYNTHETIC MODIFICATION; FUNCTIONAL-GROUPS; ADSORPTION; CLICK; TOOL; CO2;

D O I：

10.1039/c4ce01377h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rarely observed example of post-synthetically increasing pore space, while retaining the chemical functionality of the original metal-organic framework is reported. Conventional solvothermal heating in air was used to effect an efficient post-synthetic rearrangement of a bisallyloxy-tagged zinc metal-organic framework. This leads to the pore-space expanded MOF displaying a higher surface area yet lower affinity for CO2 sorption compared to the original MOF.

引用

页码：9158 / 9162

页数：5

共 50 条

[21] X-ray crystallographic insights into post-synthetic metalation products in a metal-organic framework [J].

Huxley, Michael T. ;

Coghlan, Campbell J. ;

Bloch, Witold M. ;

Burgun, Alexandre ;

Doonan, Christian J. ;

Sumby, Christopher J. .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2084)

[22] Post-synthetic cation exchange in the robust metal-organic framework MIL-101(Cr) [J].

Szilagyi, Petra A. ;

Serra-Crespo, Pablo ;

Dugulan, Iulian ;

Gascon, Jorge ;

Geerlings, Hans ;

Dam, Bernard .

CRYSTENGCOMM, 2013, 15 (47) :10175-10178

[23] Post-synthetic modification of metal-organic framework-based membranes for enhanced molecular separations [J].

Chen, Ting ;

Zhao, Dan .

COORDINATION CHEMISTRY REVIEWS, 2023, 491

[24] Luminescent Nanothermometers Obtained by Post-Synthetic Modification of Metal-Organic Framework MIL-68 [J].

Abdelhameed, Reda M. ;

Ananias, Duarte ;

Silva, Artur M. S. ;

Rocha, Joao .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (10) :1354-1359

[25] Role of hydrocarbons in pore expansion and contraction of a flexible metal-organic framework [J].

Motkuri, Radha Kishan ;

Thallapally, Praveen K. ;

Nune, Satish K. ;

Fernandez, Carlos A. ;

McGrail, B. Peter ;

Atwood, Jerry L. .

CHEMICAL COMMUNICATIONS, 2011, 47 (25) :7077-7079

[26] Post-synthetic Structural Processing in a Metal-Organic Framework Material as a Mechanism for Exceptional CO2/N2 Selectivity [J].

Bloch, Witold M. ;

Babarao, Ravichandar ;

Hill, Matthew R. ;

Doonan, Christian J. ;

Sumby, Christopher J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10441-10448

[27] Post-synthetic modification of NH2-tagged metal-organic framework: A selective, effective, and recyclable heterogeneous catalyst for CO2 conversion into cyclic carbonates [J].

Shaheed, Nuhaa ;

Nasiriani, Tahereh ;

Shaabani, Ahmad .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2024, 164

[28] Post-Synthetic Surface Modification of Metal-Organic Frameworks and Their Potential Applications [J].

Figueroa-Quintero, Leidy ;

Villalgordo-Hernandez, David ;

Delgado-Marin, Jose J. ;

Narciso, Javier ;

Velisoju, Vijay Kumar ;

Castano, Pedro ;

Gascon, Jorge ;

Ramos-Fernandez, Enrique V. .

SMALL METHODS, 2023, 7 (04)

[29] Post-synthetic modification of metal-organic frameworks for chiral gas chromatography [J].

Kou, Wen-Ting ;

Yang, Cheng-Xiong ;

Yan, Xiu-Ping .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (37) :17861-17866

[30] Simultaneously Enhanced Hydrophilicity and Stability of a Metal-Organic Framework via Post-Synthetic Modification for Water Vapor Sorption/Desorption [J].

Luo, Tian-Yi ;

Park, Sunghwan ;

Chen, Tso-Hsuan ;

Prerna ;

Patel, Roshan ;

Li, Xinyu ;

Siepmann, J. Ilja ;

Caratzoulas, Stavros ;

Xia, Zhiyong ;

Tsapatsis, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (44)

← 1 2 3 4 5 →