Synthesis of Hydroxytyrosyl Alkyl Ethers from Olive Oil Waste Waters

被引:52
作者
Madrona, Andres [1 ]
Pereira-Caro, Gema [2 ]
Mateos, Raquel [2 ]
Rodriguez, Guillermo [3 ]
Trujillo, Mariana [1 ]
Fernandez-Bolanos, Juan [3 ]
Espartero, Jose L. [1 ]
机构
[1] Univ Seville, Fac Farm, Dpto Quim Organ & Farmaceut, E-41012 Seville, Spain
[2] Ctr Venta Llano IFAPA, Jaen 23620, Spain
[3] Inst Grasa CSIC, Seville 41012, Spain
关键词
Ethers; hydroxytyrosol; natural products; antioxidants; olive oil; waste waters; ANTIOXIDANT ACTIVITY; PURIFIED HYDROXYTYROSOL; PHENOLIC-COMPOUNDS; EXTRACTION; RECOVERY; ALPERUJO; TYROSOL;
D O I
10.3390/molecules14051762
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The preparation of a new type of derivatives of the naturally occurring antioxidant hydroxytyrosol is reported. Hydroxytyrosyl alkyl ethers were obtained in high yield by a three-step procedure starting from hydroxytyrosol isolated from olive oil waste waters. Preliminary results obtained by the Rancimat method have shown that these derivatives retain the high protective capacity of free hydroxytyrosol.
引用
收藏
页码:1762 / 1772
页数:11
相关论文
共 31 条
[1]   A new process for the management of olive oil mill waste water and recovery of natural antioxidants [J].
Agalias, Apostolis ;
Magiatis, Prokopios ;
Skaltsounis, Alexios-Leandros ;
Mikros, Emmanuel ;
Tsarbopoulos, Anthony ;
Gikas, Evagelos ;
Spanos, Ioannis ;
Manios, Thrasyvoulos .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (07) :2671-2676
[2]   Agrochemical characterisation of "alperujo", a solid by-product of the two-phase centrifugation method for olive oil extraction [J].
Alburquerque, JA ;
Gonzálvez, J ;
García, D ;
Cegarra, J .
BIORESOURCE TECHNOLOGY, 2004, 91 (02) :195-200
[3]  
Alcudia F., 2004, PCT, Patent No. [2004005237, WO2004/005237]
[4]   Toward a high yield recovery of antioxidants and purified hydroxytyrosol from olive mill wastewaters [J].
Allouche, N ;
Fki, I ;
Sayadi, S .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2004, 52 (02) :267-273
[5]   Olive oil waste treatment: A comparative and critical presentation of methods, advantages & disadvantages [J].
Arvanitoyannis, Ioannis S. ;
Kassaveti, Aikaterini ;
Stefanatos, Stelios .
CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, 2007, 47 (03) :187-229
[6]   Phenolic molecules in virgin olive oils:: a survey of their sensory properties, health effects, antioxidant activity and analytical methods.: An overview of the last decade [J].
Bendini, Alessandra ;
Cerretani, Lorenzo ;
Carrasco-Pancorbo, Alegria ;
Gomez-Caravaca, Ana Maria ;
Segura-Carretero, Antonio ;
Fernandez-Gutierrez, Alberto ;
Lercker, Giovanni .
MOLECULES, 2007, 12 (08) :1679-1719
[7]   Convenient synthesis of hydroxytyrosol and its lipophilic derivatives from tyrosol or homovanillyl alcohol [J].
Bernini, Roberta ;
Mincione, Enrico ;
Barontini, Maurizio ;
Crisante, Fernanda .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (19) :8897-8904
[8]   The occurrence in olive oil of a new class of phenolic compounds: hydroxy-isochromans [J].
Bianco, A ;
Coccioli, F ;
Guiso, M ;
Marra, C .
FOOD CHEMISTRY, 2002, 77 (04) :405-411
[9]  
Bianco A, 2006, STUD NAT PROD CHEM, V33, P859
[10]  
CAPASSO R, 1994, AGROCHIMICA, V38, P165