Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides

被引：26
作者：
Kitano, Hiroyuki [1 ]
Ito, Hideto [2 ,3 ]
Itami, Kenichiro [1 ,2 ,3 ]
机构：
[1] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Nagoya Univ, JST ERATO, Itami Mol Nanocarbon Project, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 08期
关键词：
N-HETEROCYCLIC CARBENE; CROSS-COUPLING REACTIONS; (NHC)PD(ALLYL)CL NHC; PHENOL DERIVATIVES; AROMATIC AMIDES; SUZUKI-MIYAURA; BOND FORMATION; COMPLEXES; ACYLOXYLATION; ACTIVATION;
D O I：
10.1021/acs.orglett.8b00775
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first palladium-catalyzed esterification of carboxylic acids with aryl iodides is described. A palladium-based catalytic system consisting of IBnF (1,3-bis((pentafluorophenyl)methyl)imidazole-2-ylidene) ligand was found to significantly accelerate the aryl-O bond-forming esterification reaction. A series of aryl iodides and carboxylic acids undergoes a palladium-catalyzed coupling reaction to provide the corresponding aryl esters in moderate to good yields. In addition, sterically hindered aryl iodides and carboxylic acids were well-tolerated yielding the corresponding aryl esters.
引用
收藏
页码：2428 / 2432
页数：5
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