Migration of antimony from polyethylene terephthalate used in mineral water bottles

被引：71

作者：

Carneado, S. ^{[1
]}

Hernandez-Nataren, E. ^{[1
]}

Lopez-Sanchez, J. F. ^{[1
]}

Sahuquillo, A. ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Anal, E-08028 Barcelona, Spain

来源：

FOOD CHEMISTRY | 2015年 / 166卷

关键词：

Migration; Antimony speciation; Water; Inductively coupled plasma-mass; spectrometry; Polyethylene terephthalate bottle; PET CONTAINERS; DRINKING-WATER; HYDRIDE GENERATION; SPECIATION; CONTAMINATION; SPECTROMETRY; ENVIRONMENT; CATALYSTS;

D O I：

10.1016/j.foodchem.2014.06.041

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The influence of storage time and temperature on Sb migration from PET bottles into mineral water was studied in short-term tests lasting up to 15 days and long-term studies lasting up to 220 days. Samples purchased were stored in three different coloured bottles: clear (CL), light blue (LB) and dark blue (DB). Sb migration was assayed by HG-AFS for total determination and HPLC-ICP-MS for speciation analysis. Migration studies showed that waters stored at 4 and 20 degrees C were not subject to Sb migration. At 40 degrees C there was a significant increase in Sb concentration, although the maximum limit established by the European Union (5.0 mu g L-1) was not exceeded, whereas at 60 degrees C samples were subject to considerable Sb migration after 30 days of storage. In this case, the maximum limit established by the European Union was exceeded and both Sb (V) and Sb (III) were detected. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：544 / 550

页数：7

共 28 条

[1] The cause of the grey discoloration of PET prepared by the use of antimony-catalysts [J].

Aharoni, SM .

POLYMER ENGINEERING AND SCIENCE, 1998, 38 (07) :1039-1047

[2] MIGRATION FROM POLYETHYLENE TEREPHTHALATE UNDER ALL CONDITIONS OF USE [J].

ASHBY, R .

FOOD ADDITIVES AND CONTAMINANTS, 1988, 5 :485-492

[3] Effect of temperature on the release of intentionally and non-intentionally added substances from polyethylene terephthalate (PET) bottles into water: Chemical analysis and potential toxicity [J].

Bach, Cristina ;

Dauchy, Xavier ;

Severin, Isabelle ;

Munoz, Jean-Francois ;

Etienne, Serge ;

Chagnon, Marie-Christine .

FOOD CHEMISTRY, 2013, 139 (1-4) :672-680

[4] Antimony ethylene glycolate and catecholate compounds: Structural characterization of polyesterification catalysts [J].

Biros, SM ;

Bridgewater, BM ;

Villeges-Estrada, A ;

Tanski, JM ;

Parkin, G .

INORGANIC CHEMISTRY, 2002, 41 (15) :4051-4057

[5] Assessment of metal contaminations leaching out from recycling plastic bottles upon treatments [J].

Cheng, Xiaoliang ;

Shi, Honglan ;

Adams, Craig D. ;

Ma, Yinfa .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2010, 17 (07) :1323-1330

[6] Effect of antimony catalyst on solid-state polycondensation of poly(ethylene terephthalate) [J].

Duh, B .

POLYMER, 2002, 43 (11) :3147-3154

[7] Antimony in the environment: a review focused on natural waters II. Relevant solution chemistry [J].

Filella, M ;

Belzile, N ;

Chen, YW .

EARTH-SCIENCE REVIEWS, 2002, 59 (1-4) :265-285

[8] Antimony in the environment: a review focused on natural waters I. Occurrence [J].

Filella, M ;

Belzile, N ;

Chen, YW .

EARTH-SCIENCE REVIEWS, 2002, 57 (1-2) :125-176

[9] Arsenic and antimony: comparative approach on mechanistic toxicology [J].

Gebel, T .

CHEMICO-BIOLOGICAL INTERACTIONS, 1997, 107 (03) :131-144

[10] Elevated antimony concentrations in commercial juices [J].

Hansen, Claus ;

Tsirigotaki, Alexandra ;

Bak, Soren Alex ;

Pergantis, Spiros A. ;

Sturup, Stefan ;

Gammelgaard, Bente ;

Hansen, Helle Ruesz .

JOURNAL OF ENVIRONMENTAL MONITORING, 2010, 12 (04) :822-824

← 1 2 3 →