Photocatalytic activities of TiO2 thin films coated on different glass substrates -: Influence of the diffused ions from the glass substrates and the properties of the TiO2 thin films

被引:0
作者
Nam, HJ [1 ]
Amemiya, T [1 ]
Murabayashi, M [1 ]
Itoh, F [1 ]
机构
[1] Yokohama Natl Univ, Grad Sch Environm & Informat Sci, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
关键词
TiO2 thin film; Na+; crystallite size; photocatalytic activity;
D O I
10.5796/electrochemistry.72.544
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Physical properties and photocatalytic activity of TiO2 thin films coated on various glass substrates were investigated in order to elucidate factors affecting the photocatalytic activity and the role of Na+ ions diffusing from glass substrates. The most predominant factor was found to be crystal size of the TiO2 thin film. The Na+ ions affected the photocatalytic activity by changing the formation temperature of anatase as well as the crystallite size of TiO2 thin film. Na+ appears not to work as a recombination center of electrons and holes contrary to the conventionally accepted mechanism.
引用
收藏
页码:544 / 549
页数:6
相关论文
共 29 条
[1]  
ANPO M, 1987, CHEM EXPRESS, V2, P193
[2]   Gas-phase oxidation of 1-butene using nanoscale TiO2 photocatalysts [J].
Cao, LX ;
Huang, AM ;
Spiess, FJ ;
Suib, SL .
JOURNAL OF CATALYSIS, 1999, 188 (01) :48-57
[3]   A history of the production and use of carbon tetrachloride, tetrachloroethylene, trichloroethylene and 1,1,1-trichloroethane in the United States: Part 2 - Trichloroethylene and 1,1,1-trichloroethane [J].
Doherty, RE .
ENVIRONMENTAL FORENSICS, 2000, 1 (02) :83-93
[4]   Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water purification [J].
Fernandez, A ;
Lassaletta, G ;
Jimenez, VM ;
Justo, A ;
GonzalezElipe, AR ;
Herrmann, JM ;
Tahiri, H ;
AitIchou, Y .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1995, 7 (1-2) :49-63
[5]   Recent advances in heterogeneous TiO2 photocatalysis [J].
Fujishima, Akira ;
Rao, Tata Narasinga .
JOURNAL OF CHEMICAL SCIENCES, 1997, 109 (06) :471-486
[6]   TiO2 photocatalysts and diamond electrodes [J].
Fujishima, A ;
Rao, TN ;
Tryk, DA .
ELECTROCHIMICA ACTA, 2000, 45 (28) :4683-4690
[7]  
FUJISHIMA A, 1995, CHEM LETT, P841
[8]  
Fujishima A., 1999, TIO2 PHOTOCATALYSIS
[9]   PHOTOCATALYTIC ACTIVITY OF ULTRA-FINE RUTILE IN METHANOL WATER SOLUTION AND DEPENDENCE OF ACTIVITY ON PARTICLE-SIZE [J].
HARADA, H ;
UEDA, T .
CHEMICAL PHYSICS LETTERS, 1984, 106 (03) :229-231
[10]   Comparison of the degradation of benzamide and acetic acid on different TiO2 photocatalysts [J].
Heintz, O ;
Robert, D ;
Weber, JV .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 135 (01) :77-80