Synthesis of alcotex/3-aminopropanoic acid polymer thin film and its structural and opto-electrical properties

被引:1
作者
Bhuvaneswari, R. [1 ]
Gajendiran, J. [1 ]
Karthikeyan, S. [3 ]
Selvasekarapandian, S. [2 ,4 ]
Gnanam, S. [5 ]
机构
[1] Vel Tech Rangarajan Dr Sagunthala R&D Inst Sci &, Chennai 600062, Tamil Nadu, India
[2] Mat Res Ctr, Coimbatore 641045, Tamil Nadu, India
[3] Madras Christian Coll, Dept Phys, Chennai 600059, Tamil Nadu, India
[4] Bharathiar Univ, Dept Phys, Coimbatore 641046, Tamil Nadu, India
[5] Vels Inst Sci Technol & Adv Studies VISTAS, Sch Basic Sci, Dept Phys, Chennai 600117, Tamil Nadu, India
关键词
Polymers; Thin films; Structural; Optical materials and properties; Electrical properties; IONIC LIQUID; AMINO-ACID; PVA;
D O I
10.1016/j.matlet.2020.128690
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report that alcotex/3-aminopropanoic acid (PVA-beta-alanine) polymer thin film was synthesized by taking different concentrations of PVA-beta-alanine by the solution casting process, and their structural, opto-electrical and ionic conductivity were examined for the first time. In the X-ray diffraction (XRD) study, the crystallite structure of the semi-crystalline film can be clearly seen with an increase in beta-alanine and a decrease in the PVA concentrations. The presence of functional groups and optical response was analyzed for the prepared material using the Fourier Transform Infrared (FT-IR) and optical absorption tests. The wider optical band gap values are calculated to be 4.89 to 5.07 eV using the Tauc plots for polymer thin film materials at various PVA-beta-alanine concentrations. The effects of various PVA/beta-alanine wt% concentrations on the ionic conductivity, electrochemical impedance spectroscopy (EIS) parameters, power-law exponent (n) and hopping frequency of the prepared polymer films have been elucidated. (C) 2020 Elsevier B.V. All rights reserved.
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页数:3
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