Synthesis and Structural Characterization of Two Half-Sandwich Nickel(II) Complexes with the Scorpionate Ligands

被引：5

作者：

Wang, G. -F. ^{[1
]}

Zhang, X. ^{[2
]}

Sun, S. -W. ^{[1
]}

Sun, H. ^{[1
]}

Ma, H. -X. ^{[1
]}

机构：

[1] Yuncheng Univ, Dept Appl Chem, Yuncheng 044000, Peoples R China

[2] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Heilongjiang 150080, Peoples R China

来源：

CRYSTALLOGRAPHY REPORTS | 2015年 / 60卷 / 07期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-PARAMAGNETIC-RESONANCE; BIOINORGANIC PERSPECTIVES; TRANSITION-METALS; HIGH-FREQUENCY; TRIS(PYRAZOLYL)BORATE; CHEMISTRY; ACTIVATION; BORON;

D O I：

10.1134/S1063774515070299

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k(3)-N, N',N ''-Tp(t-Bu,Me) NiI] (1) and [k (3)-N,N',N ''-Tp(t-Bu,Me) NiNO3] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II) ion of complex 1 is in a four-coordinate environment, in which the donor atoms are provided by three nitrogen atoms of a hydrotris(pyrazolyl) borate ligand and one iodide atom, while that of complex 2 is in a five-coordinate environment with three nitrogen atoms from a hydrotris(pyrazolyl)borate ligand and two oxygen atoms from a nitrate ion.

引用

页码：1032 / 1037

页数：6

共 28 条

[1] A redetermination of chlorido[hydrido-tris(3-tert-butyl-5-methylpyrazolyl)-borato]nickel(II) [J].

Beitelman, Adam D. ;

Ferrence, Gregory M. .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2520-U768

[2] Structural characterization of tris(pyrazolyl)hydroborato and tris(2-pyridylthio)methyl lithium compounds: Lithium in uncommon trigonal pyramidal and trigonal monopyramidal coordination environments [J].

Chakrabarti, Neena ;

Sattler, Wesley ;

Parkin, Gerard .

POLYHEDRON, 2013, 58 :235-246

[3] Steric Titration of Arylthiolate Coordination Modes at Pseudotetrahedral Nickel(II) Centers [J].

Chattopadhyay, Swarup ;

Deb, Tapash ;

Petersen, Jeffrey L. ;

Young, Victor G., Jr. ;

Jensen, Michael P. .

INORGANIC CHEMISTRY, 2010, 49 (02) :457-467

[4] CONVENIENT SYNTHESIS, STRUCTURE, AND PROPERTIES OF [(HB(PZ)3)FECL3]-1 [J].

CHO, SH ;

WHANG, D ;

HAN, KN ;

KIM, K .

INORGANIC CHEMISTRY, 1992, 31 (03) :519-522

[5] Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH2) bonds of d6 transition metals as a potential key step in hydrocarbon functionalization:: A computational study [J].

Cundari, Thomas R. ;

Grimes, Thomas V. ;

Gunnoe, T. Brent .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :13172-13182

[6] Electronic structure of four-coordinate C3v nickel(II) scorpionate complexes:: Investigation by high-frequency and -field electron paramagnetic resonance and electronic absorption spectroscopies [J].

Desrochers, Patrick J. ;

Telser, Joshua ;

Zvyagin, S. A. ;

Ozarowski, Andrew ;

Krzystek, J. ;

Vicic, David A. .

INORGANIC CHEMISTRY, 2006, 45 (22) :8930-8941

[7] Immobilized Boron-Centered Heteroscorpionates: Heterocycle Metathesis and Coordination Chemistry [J].

Desrochers, Patrick J. ;

Besel, Brian M. ;

Corken, Adam L. ;

Evanov, Jared R. ;

Hamilton, Andrea L. ;

Nutt, David L. ;

Tarkka, Richard M. .

INORGANIC CHEMISTRY, 2011, 50 (05) :1931-1941

[8] A stable monomeric nickel borohydride [J].

Desrochers, PJ ;

LeLievre, S ;

Johnson, RJ ;

Lamb, BT ;

Phelps, AL ;

Cordes, AW ;

Gu, WW ;

Cramer, SP .

INORGANIC CHEMISTRY, 2003, 42 (24) :7945-7950

[9] Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)2Cl [J].

Foley, Nicholas A. ;

Abernethy, Robyn J. ;

Gunnoe, T. Brent ;

Hill, Anthony F. ;

Boyle, Paul D. ;

Sabat, Michal .

ORGANOMETALLICS, 2009, 28 (01) :374-377

[10] Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes [J].

Forshaw, Adam P. ;

Smith, Jeremy M. ;

Ozarowski, Andrew ;

Krzystek, J. ;

Smirnov, Dmitry ;

Zvyagin, S. A. ;

Harris, T. David ;

Karunadasa, Hemamala I. ;

Zadrozny, Joseph M. ;

Schnegg, Alexander ;

Holldack, Karsten ;

Jackson, Timothy A. ;

Alamiri, Ahmad ;

Barnes, Diane M. ;

Telser, Joshua .

INORGANIC CHEMISTRY, 2013, 52 (01) :144-159

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