Synthesis of Sb2Se3 and Bi2Se3 Nanoparticles in Ionic Liquids at Low Temperatures and Solid State Structure of [C4C1Im]3[BiCl6]

被引：11
|
作者：
Loor, Manuel [1 ,2 ]
Bendt, Georg [1 ,2 ]
Schaumann, Julian [1 ,2 ]
Hagemann, Ulrich [3 ]
Heidelmann, Markus [3 ]
Woelper, Christoph [1 ,2 ]
Schulz, Stephan [1 ,2 ]
机构：
[1] Univ Duisburg Essen, Inorgan Chem, Univ Str 5-7,S07 S03 C30, D-45117 Essen, Germany
[2] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, Univ 5-7,S07 S03 C30, D-45117 Essen, Germany
[3] NETZ, ICAN, Carl Benz Str 199, D-47047 Duisburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 01期
关键词：
Bismuth; Antimony; Selenium; Thermoelectric material; Ionic liquids; MICROWAVE-ASSISTED SYNTHESIS; TOPOLOGICAL SURFACE-STATES; WET-CHEMICAL-SYNTHESIS; BAND-GAP ENERGY; ANTIMONY SELENIDE; ELECTRONIC-PROPERTIES; CRYSTAL-STRUCTURE; THIN-FILMS; BI2TE3; INSULATORS;
D O I：
10.1002/zaac.201600325
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline Sb2Se3 nanoparticles were prepared by reaction of SbCl3 with (Et3Si)(2)Se in the presence of oleylamine (OA) in the ionic liquid [C(4)C(1)Im]Cl, whereas the reaction of (Et3Si)(2)Se with [C(4)C(1)Im](3)[BiCl6] (1), which was obtained from the reaction of BiCl3 with [C(4)C(1)Im]Cl and structurally characterized by single-crystal X-ray diffraction, yielded Bi-rich Bi2Se3 nanoparticles. In contrast, the reaction of the reactive IL [C(4)C(1)Im](3)[Bi3I12] with (Et3Si)(2)Se in the presence of oleylamine in [C(4)C(1)Im]I gave phase-pure Bi2Se3 nanoparticles. The chemical composition of the nanoparticles was investigated by EDX, while possible surface contaminations were studied by XPS and IR spectroscopy. The morphology of the nanoparticles was studied by SEM and TEM.
引用
收藏
页码：60 / 68
页数：9
相关论文
共 50 条
  • [31] Disulfates from Low Temperature Synthesis in Ionic Liquids: (C5H6N)3Sm(S2O7)3 and (C5H6N)Bi(S2O7)2
    Weiz, Alexander
    Bruns, Joern
    Wickleder, Mathias S.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (01) : 172 - 177
  • [32] Synthesis of Bi2Te3 and (BixSb1-x)2Te3 nanoparticles using the novel IL [C4mim]3[Bi3I12]
    Loor, M.
    Bendt, G.
    Hagemann, U.
    Woelper, C.
    Assenmacher, W.
    Schulz, S.
    DALTON TRANSACTIONS, 2016, 45 (39) : 15326 - 15335
  • [33] Study of antimony selenide hole-transport material for Mo/Sb2Se3/ MAPbI3/C60/GZO/Ag heterojunction planar solar cells
    Wu, G. M.
    Tseng, C. C.
    Chang, T. W.
    Feng, W. S.
    Chen, D. W.
    SURFACE & COATINGS TECHNOLOGY, 2021, 405
  • [34] About selenidostannates.: I. : Synthesis, structure, and properties of [Sn2Se6]4-, [Sn4Se10]4- and [Sn3Se7]2-
    Fehlker, A
    Blachnik, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (03): : 411 - 418
  • [35] Novel hexagonal rods and characterization of Bi0.4Sb1.6Se3xTe3(1-x) using solid-state microwave synthesis
    Kadhim, A.
    Hmood, A.
    Abu Hassan, H.
    MATERIALS LETTERS, 2012, 81 : 31 - 33
  • [36] Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6
    P. A. Abramov
    M. N. Sokolov
    A. V. Virovets
    V. P. Fedin
    Journal of Structural Chemistry, 2009, 50 : 162 - 165
  • [37] Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6
    Abramov, P. A.
    Sokolov, M. N.
    Virovets, A. V.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (01) : 162 - 165
  • [38] Synthesis and structure of the novel mixed Sb/Se and Sb/Te containing iron carbonyl clusters [Fe3(μ3-Y)(μ3-SbMes)(CO)9] (Y = Se, Te) and [Fe3(μ3,η2:η1-SeSbMes)(μ3-SbMes)(CO)10]
    Konchenko, SN
    Pushkarevsky, NA
    Scheer, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 658 (1-2) : 204 - 209
  • [39] Controlled synthesis of (hk1) preferentially oriented Sb2Se3 rod arrays by co-evaporation for photovoltaic applications
    Park, Si-Nae
    Kim, Se-Yun
    Lee, Sang-Ju
    Sung, Shi-Joon
    Yang, Kee-Jeong
    Kang, Jin-Kyu
    Kim, Dae-Hwan
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (45) : 25900 - 25907
  • [40] New pathways in the reaction between the 1,2,4-triphosphole P3C2Bu2tCH(SiMe3)2 and selenium:: Crystal and molecular structures of three new cage compounds, P3Se4C2Bu2tCH(SiMe3)2, P3Se3C2Bu2t H2CH(SiMe3)2 and P5Se2C4Bu4t(CHSiMe3But)
    Bilgic, Sevim
    Buyukkidan, Nurgun S.
    Buyukkidan, Bulent
    Hitchcock, Peter B.
    Nixon, John F.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (26) : 5769 - 5776
12345