Effect of microwave field on the behavior of iridium(III,III,IV) sulfate complex in hydrochloric acid and chloride aqueous solutions

被引：0
作者：
Buslaev, AV [1 ]
Kuz'min, NM
Buslaeva, TM
Kravchenko, VV
机构：
[1] Russian Acad Sci, Vernadskii Inst Geochem & Analyt Chem, Moscow, Russia
[2] Lomonosov State Acad Fine Chem Technol, Moscow, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 1999年 / 72卷 / 07期
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D O I：
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中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The effect of microwave field on the behavior of iridium(III,III,IV) oxosulfate, [Ir-3(mu(3)-O)(SO4)(6). (H2O)(3)](4-), in hydrochloric acid and chloride aqueous solutions was studied. Strong differences in behavior of the [Ir-3(mu(3)-O)(SO4)(6)(H2O)(3)](4-) complex in hydrochloric acid solutions in microwave field and under convection heating were revealed. Based on data of molecular spectroscopy, the sequence of transformations depending on heating conditions is discussed.
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页码：1116 / 1119
页数：4
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