Clean-up of oily liquids, fuels and organic solvents from the contaminated water fields using poly(propylene glycol) based organogels

被引:28
作者
Demirel, Yagmur Tezcan [1 ]
Yati, Ilker [1 ]
Donmez, Rahim [1 ]
Sonmez, Hayal Bulbul [1 ]
机构
[1] Gebze Tech Univ, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey
关键词
Poly(propylene glycol); Tris[3-(trimethoxysily1) propyll; isocyanurate; Organogel; Absorption; Desorption; Reusability; ABSORBENT MICROSPHERES PREPARATION; CROSS-LINKED POLY(ORTHOSILICATE)S; BUTYL ETHER MTBE; SWELLING PROPERTIES; SELECTIVE ABSORPTION; RECYCLABLE SORBENT; SPILL; SORPTION; REMOVAL; POLYMER;
D O I
10.1016/j.cej.2016.11.124
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Organogels with high and fast absorption properties, as well as reusability functions, were successfully prepared through the condensation reactions of different molecular weights of poly(propylene glycol)s (PPG)s and tris[3-(trimethoxysilyl) propyl] isocyanurate (ICS). The characterization of these organogels was determined by solid-state C-13 and Si-29 cross polarization magic angle spinning (CPMAS) nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR). Thermal gravimetric analysis (TGA) was used to describe the thermal behavior of the prepared organogels. Obtained organogels are reusable and can absorb a large amount of oils, such as dichloromethane (DCM), tetrahydrofuran (THF), methyl tert-butyl ether (MTBE), toluene, benzene, acetone, and gasoline. The capacity of the synthesized organogels did not change in either pure organic liquids or in organic liquid/water mixtures, these can be used at least ten times without loss of capacity. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:126 / 135
页数:10
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