N-heterocyclic carbenes: Reaction to give anilines

被引:18
作者
Randell, Kris [1 ]
Stanford, Matthew J. [1 ]
Clarkson, Guy J. [1 ]
Rourke, Jonathan P. [1 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
关键词
NHC; palladium; imidazolium; acetate;
D O I
10.1016/j.jorganchem.2006.04.034
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The attempted synthesis of bis(NHC)palladium complexes via the direct reaction of an imidazolium salt with palladium acetate results in the formation of a mixed NHC/aniline complex. The route by which the aniline is formed has not been completely elucidated, but it does originally derive from an imidazolium salt. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3411 / 3415
页数:5
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