Synthesis and X-ray crystal structure of pyrrolo[1,2-a]benzimidazoles

被引：13
作者：
Awadallah, Adel M.
Seppelt, Konrad
Shorafa, Hashem
机构：
[1] Islam Univ, Fac Sci, Dept Chem, Gaza, Palestine, Israel
[2] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany
来源：
TETRAHEDRON | 2006年 / 62卷 / 33期
关键词：
nitrilimines; 2-cyanomethylbenzimidazole; 2-aminobenzimidazole; pyrrolo[1,2-alpha]benzimidazole;
D O I：
10.1016/j.tet.2006.05.071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of nitrilimines 1 with 2-cyanomethylbenzimidazole 2 gave the 3-arylazo-2-methylpyrrolo[1,2-a]benzimidazole 4a rather than the reported 2-arylazo-3-methylpyrrolo[1,2-a]benzimidazole 3a. The correct structure of the product was determined using X-ray crystal structure analysis. The similar reaction of nitrilimines with 2-aminobenzimidazole 5 gave the acyclic nucleophilic addition product 6. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7744 / 7746
页数：3
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