Production of pure hydrogen from methane by low temperature plasma processing

被引:7
作者
Cho, Dong Lyun [1 ]
Kim, Hae-Na [2 ]
Lee, Minguen [2 ]
Cho, Eunkyung [2 ]
机构
[1] Chonnam Natl Univ, Dept Appl Chem Engn, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Dept Adv Chem & Engn, Kwangju 500757, South Korea
基金
新加坡国家研究基金会;
关键词
Production of Pure Hydrogen; Methane; Low Temperature Plasma; Plasma-catalyst Hybrid System; CO2; CONVERSION; CATALYSTS; CH4; GAS;
D O I
10.1007/s11814-015-0107-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Production of pure hydrogen from methane by a low temperature plasma process coupled with catalytic reaction was investigated. In low temperature plasma, methane molecules were converted to thin solid films and hydrogen. The conversion of methane and the hydrogen yield depended on the flow rate of methane and the discharge power for the low temperature plasma process. They increased as the flow rate decreased and the discharge power increased. A conversion as high as 87.4% and hydrogen yield as high as 67% could be obtained, but the purity of the hydrogen was less than 90%. The purity could be increased to 100% by coupling the low temperature plasma process with a catalytic reaction using a plasma-catalyst hybrid system.
引用
收藏
页码:2519 / 2523
页数:5
相关论文
共 19 条
[1]   Hydrogen from photo-catalytic water splitting process: A review [J].
Ahmad, H. ;
Kamarudin, S. K. ;
Minggu, L. J. ;
Kassim, M. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 43 :599-610
[2]   Dynamics of H2 production by steam reforming [J].
Beckhaus, P ;
Heinzel, A ;
Mathiak, J ;
Roes, J .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :294-299
[3]   Plasma reforming of methane [J].
Bromberg, L ;
Cohn, DR ;
Rabinovich, A ;
O'Brien, C ;
Hochgreb, S .
ENERGY & FUELS, 1998, 12 (01) :11-18
[4]  
Cho DL, 2007, J IND ENG CHEM, V13, P287
[5]   Conversion of natural gas to C2 product, hydrogen and carbon black using a catalytic plasma reaction [J].
Cho, Wonjun ;
Kim, Young Chai ;
Kim, Seung-Soo .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2010, 16 (01) :20-26
[6]   Gaseous products from biomass by pyrolysis and gasification: effects of catalyst on hydrogen yield [J].
Demirbas, A .
ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (07) :897-909
[7]   Comparison of different applied voltage waveforms on CO2 reforming of CH4 in an atmospheric plasma system [J].
Duc Ba Nguyen ;
Lee, Won Gyu .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2015, 32 (01) :62-67
[8]  
Heinz G., 1962, Hydrocarb Process Pe.t Refin, V41, P159
[9]  
Kim Seongcheon, 2006, [Transactions of the Korean Hydrogen and New Energy Society, 한국수소및신에너지학회논문집], V17, P362
[10]   Plasma-catalyst hybrid methanol-steam reforming for hydrogen production [J].
Lee, Dae Hoon ;
Kim, Taegyu .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (14) :6039-6043