Structural and bonding characteristics in transition metal-silane complexes

被引：175

作者：

Lin, ZY ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2002年 / 31卷 / 04期

关键词：

D O I：

10.1039/b106620j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal-silane complexes containing metal-eta(2)-H-Si coordination display different structural and bonding characteristics in comparison to. other a-complexes; such as dihydrogen and, alkane (agostic) complexes. The different characteristics can be related-to the strong. sigma*-accepting properties of the eta(2)-silane ligand(s) because of the weaker H-Si sigma bond. Various: examples of metal-silane complexes have been reviewed and their structural stabilities have been systematically discussed. Silyl-hydride complexes having substantial silyl-hydrido interactions have also been emphasized.

引用

页码：239 / 245

页数：7

共 40 条

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