Core/shell structured halloysite/polyaniline nanotubes with enhanced electrochromic properties

被引：57

作者：

Hu, Fei ^{[1
]}

Xu, Jianlong ^{[2
]}

Zhang, Sihang ^{[1
]}

Jiang, Jie ^{[1
]}

Yan, Bin ^{[1
]}

Gu, Yingchun ^{[1
]}

Jiang, Mengjin ^{[3
]}

Lin, Shaojian ^{[1
]}

Chen, Sheng ^{[1
]}

机构：

[1] Sichuan Univ, Coll Light Ind Text & Food Engn, Funct Polymer Mat Lab, Chengdu 610065, Sichuan, Peoples R China

[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China

[3] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat & Engn, Chengdu 610065, Sichuan, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2018年 / 6卷 / 21期

基金：

中国国家自然科学基金;

关键词：

CONTROLLABLE GROWTH; HYBRID MATERIALS; GRAPHENE OXIDE; ENERGY-STORAGE; POLYANILINE; SHELL; COMPOSITE; NANOCOMPOSITE; PERFORMANCE; FILMS;

D O I：

10.1039/c8tc01163j

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Novel halloysite (HNT)/polyaniline (PANI) nanocomposites are fabricated by controllable in situ chemical polymerization for electrochromic applications. The nanocomposites with different morphologies can be obtained simply by controlling the relative proportions of aniline (ANI) monomers and HNTs in the chemical polymerization system. "Adsorption'' is proposed to account for the preferential growth of PANI along HNT nanotubes to form a core/shell structure. The films casted by the nanocomposites exhibited remarkably enhanced electrochromic performances. When compared with pure polyaniline, nanocomposite films possess a faster response time (1.0 s for bleaching and 3.0 s for coloring), higher optical contrast (60.5%), and more remarkable switching stability (over 500 cycles). The unique nanocomposites pave the way for developing new functional materials with enhanced properties for new applications.

引用

页码：5707 / 5715

页数：9

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