Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)

被引:0
作者
Duan, Wenzeng [1 ,3 ]
Sun, Junshan [2 ]
Ma, Yudao [3 ]
Wu, Rentao [1 ]
机构
[1] Taishan Univ, Dept Chem & Environm Sci, Tai An 271021, Shandong, Peoples R China
[2] Taishan Univ, Dept Chem & Mat Engn, Tai An 271021, Shandong, Peoples R China
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
COMPLEXES;
D O I
10.1107/S1600536809016717
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)(2)], the Cd(II) ion is heptacoordinated by two chelating 2,2'-bipyridyl ligands [Cd center dot center dot center dot N 2.370 (6)-2.416 (6) angstrom], one carboxylate O atom [Cd center dot center dot center dot O 2.290 (6) angstrom] from the trifluoroacetate ligand and two O atoms [Cd center dot center dot center dot O 2.386 (6), 2.633 (6) angstrom] from a chelating nitrate anion. The trifluoromethyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak intermolecular C-H center dot center dot center dot O hydrogen bonds contribute to the crystal packing stability.
引用
收藏
页码:M635 / U378
页数:11
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