Synthesis and characterization of a lead(II) complex with microporous structure

被引：0
作者：
Fu, ZY [1 ]
Wu, XT [1 ]
Dai, JC [1 ]
Hu, SM [1 ]
Du, WX [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 03期
关键词：
lead complex; crystal structure; three dimensions; open framework;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3-D coordination polymer [PbNH(CH2COO)(2)] 1 has been prepared under hydrothermal conditions and its crystal structure was studied by single-crystal X-ray diffraction, The compound belongs to orthorhombic system, space group Fdd2 with unit cell parameters: a = 13.6304(6), b = 36.295(1), c = 5.0821(2) Angstrom, V = 2514.19(17) Angstrom(3), Z = 16, M-r = 338.28, D-c = 3.575 g/cm(3), F(000) = 2400 and mu(MoKalpha) = 2.679 cm(-1). The final R and wR are 0.0290 and 0.0685, respectively, for 874 observed reflections with I > 2sigma(I). The lead has a distorted tetragonal pyramid environment with four oxygen donors in the basal plane and one nitrogen donor in the axial site, Micro-channels are observed in the neutral 3-D network of 1.
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页码：296 / 298
页数：3
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