Low-Cost Y-Doped TiO2 Nanosheets Film with Highly Reactive {001} Facets from CRT Waste and Enhanced Photocatalytic Removal of Cr(VI) and Methyl Orange

被引:61
作者
Zhang, Qijun [1 ]
Fu, Yu [1 ]
Wu, Yufeng [1 ]
Zhang, Yi-Nan [2 ]
Zuo, Tieyong [1 ]
机构
[1] Beijing Univ Technol, Inst Circular Econ, Beijing 100124, Peoples R China
[2] Univ Toronto, Inst Biomat & Biomed Engn, Toronto, ON M5S 3G9, Canada
关键词
CRT waste; Recycling Rare earth elements; Y-doped; TiO2; nanosheets; {001} facets; Photocatalytic activities; CATHODE-RAY TUBE; MESOPOROUS TIO2; FUNNEL GLASS; THIN-FILMS; NITROGEN; YTTRIUM; NANOCRYSTALS; FABRICATION; PERCENTAGE; REDUCTION;
D O I
10.1021/acssuschemeng.5b01783
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, efficiency recovery of rare earth elements from cathode ray tubes (CRT) waste. Moreover, recycled yttrium was also served as raw material to produce a low-cost Y-doped TiO2 nanosheets film with exposed {100} facets. An etching/dissolution growth mechanism was postulated by systematically investigating the influence of the reaction time. The synergistic effect of the Y dopant and the dominant {001} facets endows TiO2 nanosheets film with excellent activity in the photoremoval of Methyl Orange (MO) and Cr(VI). A possible mechanism of photoremoval of MO and Cr(VI) is proposed. This study not only contributes to recycling methods for CRT waste but also presents a new way to prepare low-cost sustainable photocatalytic materials using economically viable waste.
引用
收藏
页码:1794 / 1803
页数:10
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