Incorporation of silver (I) ions within zeolite cavities and their photocatalytic reactivity for the decomposition of N2O into N2 and O2

被引：14

作者：

Ju, WS ^{[1
]}

Matsuoka, M ^{[1
]}

Anpo, M ^{[1
]}

机构：

[1] Univ Osaka Prefecture, Grad Sch Engn, Dept Appl Chem, Osaka 5998531, Japan

来源：

INTERNATIONAL JOURNAL OF PHOTOENERGY | 2003年 / 5卷 / 01期

关键词：

D O I：

10.1155/S1110662X03000060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ag+/ZSM-5 catalysts were prepared by an ion-exchange method. UV-irradiation of the Ag+/ ZSM-5 catalysts in the presence of N2O led to the photocatalytic decomposition of N2O into N-2 and O-2 at 298 K. Investigations of the effective wavelength of the irradiated UV-light for the reaction as well as the in-situ characterization of the catalysts by means of UV-Vis, photoluminescence and FT-IR spectroscopies revealed that the photoexcitation of the Ag+ - N2O complexes formed between gaseous N2O and the isolated Ag+ ions exchanged within the zeolite cavities plays a significant role in the reaction.

引用

页码：17 / 19

页数：3

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