Pyridinium linkers and mixed anions in cationic metal-organic frameworks

被引：27

作者：

Lin, Jian-Bin ^{[1
]}

Shimizu, George K. H. ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

INORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 04期

关键词：

CARBON-DIOXIDE CAPTURE; COORDINATION POLYMER; ADSORPTION; THERMODYNAMICS;

D O I：

10.1039/c3qi00065f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pyridinium linkers direct the formation of a cationic metal organic framework [Cu(ipq)]A (where H(2)ipq(+) = 1-(3,5-dicarboxyphenyl)-4-( pyridin-4-yl)pyridinium, A(-) = NO3-, BF4-, BF4-/PF6-), CALF-32(A), where intra-pore anions can be varied and mixed to control porosity and gas uptake.

引用

页码：302 / 305

页数：4

共 29 条

[1] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+

[2] Heterometallic Modular Metal-Organic 3D Frameworks Assembled via New Tris-β-Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests [J].

Carlucci, Lucia ;

Ciani, Gianfranco ;

Maggini, Simona ;

Proserpio, Davide M. ;

Visconti, Marco .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (41) :12328-12341

[3] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].

Caskey, Stephen R. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+

[4] New Zn-Aminotriazolate-Dicarboxylate Frameworks: Synthesis, Structures, and Adsorption Properties [J].

Chen, Kai-Jie ;

Lin, Rui-Biao ;

Liao, Pei-Qin ;

He, Chun-Ting ;

Lin, Jian-Bin ;

Xue, Wei ;

Zhang, Yue-Biao ;

Zhang, Jie-Peng ;

Chen, Xiao-Ming .

CRYSTAL GROWTH & DESIGN, 2013, 13 (05) :2118-2123

[5] Broadly hysteretic H2 adsorption in the microporous metal-organic framework Co(1,4-benzenedipyrazolate) [J].

Choi, Hye Jin ;

Dinca, Mircea ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :7848-+

[6] Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction [J].

Dietzel, Pascal D. C. ;

Johnsen, Rune E. ;

Fjellvag, Helmer ;

Bordiga, Silvia ;

Groppo, Elena ;

Chavan, Sachin ;

Blom, Richard .

CHEMICAL COMMUNICATIONS, 2008, (41) :5125-5127

[7] Fine-Tuning Pore Size by Shifting Coordination Sites of Ligands and Surface Polarization of Metal-Organic Frameworks To Sharply Enhance the Selectivity for CO2 [J].

Du, Liting ;

Lu, Zhiyong ;

Zheng, Kaiyuan ;

Wang, Junyi ;

Zheng, Xin ;

Pan, Yi ;

You, Xiaozeng ;

Bai, Junfeng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) :562-565

[8] Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+•••I- interactions and modification of the structures and properties of MOFs [J].

Fu, Junhong ;

Li, Huijun ;

Mu, Yajuan ;

Hou, Hongwei ;

Fan, Yaoting .

CHEMICAL COMMUNICATIONS, 2011, 47 (18) :5271-5273

[9] Topological control in heterometallic metal-organic frameworks by anion templating and metalloligand design [J].

Halper, Sara R. ;

Do, Loi ;

Stork, Jay R. ;

Cohen, Seth M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15255-15268

[10] Porous Coordination Polymer with Pyridinium Cationic Surface, [Zn2(tpa)2(Cpb)] [J].

Higuchi, Masakazu ;

Tanaka, Daisuke ;

Horike, Satoshi ;

Sakamoto, Hirotoshi ;

Nakamura, Kohei ;

Takashima, Yohei ;

Hijikata, Yuh ;

Yanai, Nobuhiro ;

Kim, Jungeun ;

Kato, Kenichi ;

Kubota, Yoshiki ;

Takata, Masaki ;

Kitagawa, Susumu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (30) :10336-+

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