Novel homo- and heterobimetallic palladium(0) and platinum(0) complexes of olefinic mono-, bis-, and tris-macrocyclic ligands

被引：19

作者：

Masllorens, J

Roglans, A

Moreno-Mañas, M

Parella, T

机构：

[1] Univ Girona, Dept Chem, Girona 17071, Spain

[2] Univ Autonoma Barcelona, Dept Chem, Barcelona 08193, Spain

[3] Univ Autonoma Barcelona, Serv RMN, Barcelona, Spain

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 11期

关键词：

D O I：

10.1021/om049967s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molecular structures featuring two and three triolefinic 15-membered macrocycles of type 2 as well as their homo- and heterometallic complexes of palladium(0) and platinum(0) (5, 7) have been synthesized from 2,4,6-trichloro-1,3,5-triazine, 1. The strategy employed allows easy preparation of heterobimetallic complexes in a controlled manner. Several mass spectrometry techniques are useful to identify these complexes.

引用

页码：2533 / 2540

页数：8

共 14 条

[11] SYNTHESIS AND CHEMISTRY OF NEW COMPLEXES OF PALLADIUM(0) AND PLATINUM(0) WITH CHELATING PHOSPHINE AMIDE LIGANDS - X-RAY STRUCTURE OF CIS-BIS(ORTHO-(DIPHENYLPHOSPHINO)-N-BENZOYLANILINO)PALLADIUM(II)
PARK, S
HEDDEN, D
RHEINGOLD, AL
ROUNDHILL, DM
ORGANOMETALLICS, 1986, 5 (07) : 1305 - 1311
[12] ELECTRONIC EFFECTS OF MONO-(TRIMETHYLSILYL)-METHYL, BIS-(TRIMETHYLSILYL)-METHYL, AND TRIS-(TRIMETHYLSILYL)-METHYL GROUPS . F-19 NUCLEAR MAGNETIC RESONANCE SPECTRA OF META AND PARA ME3SI)XCH(3-X)!C6H4F COMPOUNDS (X=0-3)
BASSINDA.AR
EABORN, C
WALTON, DRM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 21 (01) : 91 - &
[13] RIGID BIDENTATE NITROGEN LIGANDS IN ORGANOMETALLIC CHEMISTRY AND HOMOGENEOUS CATALYSIS .7. ZEROVALENT PALLADIUM AND PLATINUM COMPLEXES CONTAINING RIGID BIDENTATE NITROGEN LIGANDS AND ALKENES - SYNTHESIS, CHARACTERIZATION, ALKENE ROTATION AND SUBSTITUTION-REACTIONS - X-RAY CRYSTAL-STRUCTURE OF [BIS((2,6-DIISOPROPYLPHENYL)IMINO)ACENAPHTHENE](MALEIC ANHYDRIDE)PALLADIUM(0)
VANASSELT, R
ELSEVIER, CJ
SMEETS, WJJ
SPEK, AL
INORGANIC CHEMISTRY, 1994, 33 (07) : 1521 - 1531
[14] HETERODIFUNCTIONAL LIGANDS DERIVED FROM MONOOXIDIZED BIS(PHOSPHINO)AMINES - SYNTHESIS AND TRANSITION-METAL (MOLYBDENUM(0), TUNGSTEN(0), RHODIUM(I), PALLADIUM(II), AND PLATINUM(II)) COMPLEXES OF (DIPHENYLPHOSPHINO)(DIPHENYLPHOSPHINOTHIOYL)- AND (DIPHENYLPHOSPHINO)(DIPHENYLPHOSPHINOSELENOYL)PHENYLAMINE, PH(2)PN(PH)P(E)PH(2) (E=S, SE) - CRYSTAL AND MOLECULAR-STRUCTURE OF THE PT(II) COMPLEX [CL(2)PTPPH(2)N(PH)P(S)PH(2)]CENTER-DOT-H2O
BALAKRISHNA, MS
KLEIN, R
UHLENBROCK, S
PINKERTON, AA
CAVELL, RG
INORGANIC CHEMISTRY, 1993, 32 (25) : 5676 - 5681

← 1 2 →