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Novel homo- and heterobimetallic palladium(0) and platinum(0) complexes of olefinic mono-, bis-, and tris-macrocyclic ligands
被引:19
|作者:
Masllorens, J
Roglans, A
Moreno-Mañas, M
Parella, T
机构:
[1] Univ Girona, Dept Chem, Girona 17071, Spain
[2] Univ Autonoma Barcelona, Dept Chem, Barcelona 08193, Spain
[3] Univ Autonoma Barcelona, Serv RMN, Barcelona, Spain
关键词:
D O I:
10.1021/om049967s
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Molecular structures featuring two and three triolefinic 15-membered macrocycles of type 2 as well as their homo- and heterometallic complexes of palladium(0) and platinum(0) (5, 7) have been synthesized from 2,4,6-trichloro-1,3,5-triazine, 1. The strategy employed allows easy preparation of heterobimetallic complexes in a controlled manner. Several mass spectrometry techniques are useful to identify these complexes.
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页码:2533 / 2540
页数:8
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