Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]•H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

被引：7
|
作者：
Xu, Ning [1 ]
Xing, Yan [1 ]
Liu, Xianchun [1 ]
Song, Danhui [1 ]
Ma, Ling [1 ]
Sun, Xiujuan [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 03期
关键词：
Neodymium; Crystal engineering; Organic-inorganic hybrid composites; Luminescence; Open framework; COORDINATED ORGANONITROGEN LIGANDS; OPEN-FRAMEWORK STRUCTURES; RARE-EARTH SULFATES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; PHOSPHITE; PILLARS; CHAINS; KAGOME; PHEN;
D O I：
10.1002/zaac.200801309
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An organically templated neodymium oxalate-sulfate [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. In 1, the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate-sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.
引用
收藏
页码：558 / 562
页数：5
相关论文
共 50 条
  • [41] Structural features of a new [Fe(nicotinamide)2(H2O)4]•[Fe(H2O)6]• (SO4)2•2H2O complex
    Çakir, S
    Biçer, E
    Aoki, K
    Coskun, E
    CRYSTAL RESEARCH AND TECHNOLOGY, 2006, 41 (03) : 314 - 320
  • [42] Synthesis and structure of organically templated lanthanum sulfate [C4N3H16][La(SO4)3]•H2O
    Xing, Y
    Liu, YL
    Shi, Z
    Meng, H
    Pang, WQ
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 174 (02) : 381 - 385
  • [43] BARIUM COPPER(II) OXOCARBON COMPOUNDS - SYNTHESIS, CRYSTAL-STRUCTURES AND THERMAL BEHAVIORS OF [BA(H2O)(5)][CU(C2O4)(2)(H2O)] AND [BA(C4O4)(0.5)(H2O)(2)](2)[CU(C4O4)(2)(H2O)(2)]
    BOUAYAD, A
    TROMBE, JC
    GLEIZES, A
    INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 1 - 7
  • [44] Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2]•6H2O
    Narsimhulu, M.
    Kumar, G. Anil
    Bhargavi, G.
    Srinivas, B.
    Hussain, K. A.
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1178 : 155 - 161
  • [45] Crystal structure of a three-dimensional neodymium(III) coordination polymer, [Nd2(H2O)6(glutarato)(SO4)2]n
    Yimklan, Saranphong
    Chimupala, Yothin
    Wongngam, Sutsiri
    Kaeosamut, Nippich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 159 - +
  • [46] Two new diamine templated lanthanum sulfates, La2(H2O)2(C4H12N2)(SO4)4 and La2(H2O)2(C2H10N2)3(SO4)6•4H2O, with 3D and 2D crystal structures
    Bataille, T
    Louër, D
    JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) : 3487 - 3493
  • [47] (C3H12N2)2[UO2(H2O)2(SO4)2]2•2H2O:: an organically templated uranium sulfate with a novel dimer type
    Doran, MB
    Norquist, AJ
    O'Hare, D
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M881 - M884
  • [48] Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles
    L. I. Yudanova
    A. V. Ishchenko
    N. A. Rudina
    Russian Journal of Physical Chemistry A, 2021, 95 : 1663 - 1670
  • [49] Thermal Decomposition of [Cu(H2O)2(C8H4O4)], [CuNi(H2O)4(C8H4O4)2], and [Ni(H2O)2(C8H4O4)2](H2O)2 with the Formation of Metal and Bimetal Nanoparticles
    Yudanova, L., I
    Ishchenko, A., V
    Rudina, N. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (08) : 1663 - 1670
  • [50] Reversible Photochromic Properties of Ti2O3(H2O)2(C2O4) . H2O Material
    Hu, Kangkai
    Lei, E.
    Zhao, Dan
    Guo, Zhengang
    Zhang, Bo
    CHEMNANOMAT, 2022, 8 (01)
12345