Synthesis, Structure and Photoluminescent Properties of [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]•H2O, a New Organically Templated Neodymium(III) Oxalate-sulfate

被引：7

作者：

Xu, Ning ^{[1
]}

Xing, Yan ^{[1
]}

Liu, Xianchun ^{[1
]}

Song, Danhui ^{[1
]}

Ma, Ling ^{[1
]}

Sun, Xiujuan ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 03期

关键词：

Neodymium; Crystal engineering; Organic-inorganic hybrid composites; Luminescence; Open framework; COORDINATED ORGANONITROGEN LIGANDS; OPEN-FRAMEWORK STRUCTURES; RARE-EARTH SULFATES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; PHOSPHITE; PILLARS; CHAINS; KAGOME; PHEN;

D O I：

10.1002/zaac.200801309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An organically templated neodymium oxalate-sulfate [C6N2H14][Nd-2(C2O4)(2)(SO4)(2)(H2O)(4)]center dot H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction analysis. In 1, the neodymium(III) ions are interconnected through oxalate and sulfate groups to form a neodymium oxalate-sulfate hybrid structure. A luminescence spectrum of 1 was recorded, and the luminescence decay time was also measured.

引用

页码：558 / 562

页数：5

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