Catalytic asymmetric carbonyl-ene reactions with alkynylogous and vinylogous glyoxylates: Application to controlled synthesis of chiral isocarbacyclin analogues

被引：34
|
作者：
Mikami, K
Yoshida, A
Matsumoto, Y
机构：
[1] Department of Chemical Technology, Tokyo Institute of Technology, Tokyo 152, Meguro-ku
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 47期
关键词：
D O I：
10.1016/0040-4039(96)01954-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The asymmetric carbonyl-ene reaction with alkynylogous and vinylogous glyoxylates (1, 2) catalyzed by a binaphthol-derived chiral titanium complex is described. The catalytic asymmetric ene reaction with aldehyde (I) can be applied to the double asymmetric synthesis of isocarbacyclin analogues bearing a 2-allenyl side chain. Copyright (C) 1996 Elsevier Science Ltd
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页码：8515 / 8518
页数：4
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