Triethanolamine as an Inexpensive and Efficient Ligand for Copper-Catalyzed Hydroxylation of Aryl Halides in Water

被引：34

作者：

Wang, Deping ^{[1
,2
]}

Kuang, Daizhi ^{[1
,2
]}

Zhang, Fuxing ^{[1
,2
]}

Tang, Siping ^{[1
,2
]}

Jiang, Wujiu ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan Province, Peoples R China

[2] Hengyang Normal Univ, Key Discipline Mat Phys & Chem, Five Year Plan Key Construct Disciplines Hunan Pr, Hengyang 421008, Hunan Province, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Copper; Hydroxylation; Phenols; N ligands; Water chemistry; C-N; PHENOLS; ETHERS; ARYLATION; HYDROXIDE; BROMIDES;

D O I：

10.1002/ejoc.201301370

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The CuI/triethanolamine catalyst system efficiently promotes the direct hydroxylation of aryl iodides and bromides in water to provide the corresponding phenols in good to excellent yields. Moreover, the procedure avoids the use of toxic organic solvents and tolerates many functional groups.

引用

页码：315 / 318

页数：4

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