Synthesis and Properties of Energetic 1,2,4-Oxadiazoles

被引：16

作者：

Wang, Zuoquan ^{[1
]}

Zhang, Hong ^{[1
,2
]}

Jabeen, Farukh ^{[1
]}

Gopinathan-Pillai, Girinath ^{[1
,3
]}

Arami, Justin A. ^{[1
]}

Killian, Benjamin J. ^{[1
]}

Stiegler, Kelcie D. ^{[1
]}

Yudewitz, Dalia S. ^{[1
]}

Thiemann, Pauline L. ^{[1
]}

Turk, Jessica D. ^{[1
]}

Zhou, Wenfeng ^{[4
,5
]}

Steel, Peter J. ^{[6
]}

Hall, C. Dennis ^{[1
]}

Katritzky, Alan R. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China

[3] Univ Tartu, Dept Chem, EE-50411 Tartu, Estonia

[4] China Agr Univ, Dept Appl Chem, Beijing 100193, Peoples R China

[5] Univ Idaho, Dept Chem, Moscow, ID 83843 USA

[6] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 34期

关键词：

Synthetic methods; Nitrogen heterocycles; Energetic materials; Explosives; Heat of formation; C-H FUNCTIONALIZATION;

D O I：

10.1002/ejoc.201501056

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of a series of 3,5-di-aryl-1,2,4-oxadiazoles are reported and the effects of nitro groups in the aromatic rings on the experimental heats of decomposition (Delta H-d) and heats of combustion (Delta H-c) are evaluated. Heats of formation (Delta H-f) and densities (rho) were calculated and correlations between Delta H-d and Delta H-f were assessed for these compounds. Experimental determination of rho (by gas pycnometry) on a selection of the compounds led to the calculation of detonation velocity (V-D), detonation pressure (P-D) and specific impulse (I-SP) parameters by the Explo 5 program. An X-ray analysis of compound (4i) confirmed the structure and showed a crystal density (at 120 K) close to that determined by gas pycnometry.

引用

页码：7468 / 7474

页数：7

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