Synthesis, Structure and Property of a 1D Coordination Polymer [Mn{5-(NO2)sal}2(phen)]n with 5-Nitrosalicylate Ligand

被引：0

作者：

Wen De-Cai ^{[1
]}

Xie Jing ^{[1
]}

Jiang Xiu-Rong ^{[1
]}

机构：

[1] Longyan Univ, Dept Chem, Longyan 364000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 28卷 / 03期

关键词：

coordination polymer; 5-nitrosalicylic acid; manganese(II); crystal structure; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESES; MAGNETIC-PROPERTIES; COBALT(II) COMPLEX; 1,10-PHENANTHROLINE; 3,5-DINITROSALICYLATE; NETWORKS; ACID; 2D;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer [Mn{5-(NO2)sal}(2)(phen)](n) (5-(NO2)sal = 5-nitrosalicylate, phen = 1,10-phenanthroline) was synthesized by a hydrothermal reaction and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The title complex crystallizes in orthorhombic, space group Pbcn with a = 25.747(8), b = 13.220(4), c = 7.009(3) angstrom, V = 2386(1) angstrom(3), Z = 4, R = 0.0427 and wR = 0.0890. The 5-nitrosalicylate anions doubly bridge the Mn(II) atoms to form a one-dimensional polymeric chain with repeated eight-membered ring units (Mn-O-C-O)(2). The crystal structure is stabilized by intra- and interchain hydrogen bonding interactions. The cyclic voltammetric behavior of the title complex is also reported.

引用

页码：279 / 282

页数：4

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