Esterification of Microwave Pyrolytic Oil from Palm Oil Kernel Shell

被引:7
作者
Aziz, Sharifah Mona Abdul [1 ]
Wahi, Rafeah [2 ]
Ngaini, Zainab [2 ]
Hamdan, Sinin [3 ]
Yahaya, Syamila Aimi [2 ]
机构
[1] Univ Malaysia Sarawak, Ctr Pre Univ Studies, Kota Samarahan 94300, Sarawak, Malaysia
[2] Univ Malaysia Sarawak, Fac Resource Sci & Technol, Dept Chem, Kota Samarahan 94300, Sarawak, Malaysia
[3] Univ Malaysia Sarawak, Fac Engn, Dept Mech & Mfg Engn, Kota Samarahan 94300, Sarawak, Malaysia
关键词
BIO-OIL; SEWAGE-SLUDGE; BIOMASS; ENERGY; FUELS; WATER; GAS;
D O I
10.1155/2017/8359238
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microwave pyrolysis is a potential for producing alternative fuel from biomass, such as palm kernel shell (PKS). However, the resulting microwave pyrolytic oil (bio- oil) was highly acidic and has low calorific value and therefore must undergo additional process to improve the physicochemical properties. In this study, attempt wasmade to improve the pH and calorific value of bio- oil produced from PKS via esterification process. The effect of esterification with ethanol in the presence of sulphuric acid as a catalyst on selected biodiesel qualities was also investigated. The esterification process has successfully improved the pH value from 3.37 to 5.09- 5.12 and the calorific value was increased from 27.19 to 34.78- 41.52MJ/ kg. Conclusively, the EO has comparatively better properties in terms of its smell, pH, calorific value, and absence of environmentally undesirable compounds. However, future works should include ASTM 6751 specifications tests for biodiesel to evaluate the bio- oil's suitability for commercial use.
引用
收藏
页数:8
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共 21 条
[1]   Microwave technology for energy-efficient processing of waste [J].
Appleton, TJ ;
Colder, RI ;
Kingman, SW ;
Lowndes, IS ;
Read, AG .
APPLIED ENERGY, 2005, 81 (01) :85-113
[2]   Conventional and microwave induced pyrolysis of coffee hulls for the production of a hydrogen rich fuel gas [J].
Dominguez, A. ;
Menendez, J. A. ;
Fernandez, Y. ;
Pis, J. J. ;
Nabais, J. M. Valente ;
Carrott, P. J. M. ;
Carrott, M. M. L. Ribeiro .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2007, 79 (1-2) :128-135
[3]   Production of bio-fuels by high temperature pyrolysis of sewage sludge using conventional and microwave heating [J].
Domínguez, A ;
Menéndez, JA ;
Inguanzo, M ;
Pís, JJ .
BIORESOURCE TECHNOLOGY, 2006, 97 (10) :1185-1193
[4]   Investigations into the control of odour and viscosity of biomass oil derived from pyrolysis of sewage sludge [J].
Doshi, VA ;
Vuthaluru, HB ;
Bastow, T .
FUEL PROCESSING TECHNOLOGY, 2005, 86 (08) :885-897
[5]   Pyrolysis of the Moroccan (Tarfaya) oil shales under microwave irradiation [J].
El harfi, K ;
Mokhlisse, A ;
Chanâa, MB ;
Outzourhit, A .
FUEL, 2000, 79 (07) :733-742
[6]   Characterization of bio-oils in chemical families [J].
Garcia-Perez, M. ;
Chaala, A. ;
Pakdel, H. ;
Kretschmer, D. ;
Roy, C. .
BIOMASS & BIOENERGY, 2007, 31 (04) :222-242
[7]   Catalytic esterification of model compounds of biomass pyrolysis oil [J].
Guo Zuo-gang ;
Wang Shu-rong ;
Zhu Ying-ying .
ICEET: 2009 INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT TECHNOLOGY, VOL 1, PROCEEDINGS, 2009, :545-547
[8]   Total recovery of resources and energy from rice straw using microwave-induced pyrolysis [J].
Huang, Y. F. ;
Kuan, W. H. ;
Lo, S. L. ;
Lin, C. F. .
BIORESOURCE TECHNOLOGY, 2008, 99 (17) :8252-8258
[9]   Effect of water on sulfuric acid catalyzed esterification [J].
Liu, YJ ;
Lotero, E ;
Goodwin, JG .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 245 (1-2) :132-140
[10]   Microwave-induced pyrolysis of plastic wastes [J].
Ludlow-Palafox, C ;
Chase, HA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (22) :4749-4756