A mixed-valence tin-oxygen cluster containing six peripheral ferrocene units

被引：126

作者：

Zheng, GL ^{[1
]}

Ma, JF ^{[1
]}

Su, ZM ^{[1
]}

Yan, LK ^{[1
]}

Yang, J ^{[1
]}

Li, YY ^{[1
]}

Liu, JF ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 18期

关键词：

cluster compounds; cyclic voltammetry; cyclopentadienyl ligands; mixed-valent compounds; tin;

D O I：

10.1002/anie.200353359

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dealkylation of nBu2SnO with 1,1-ferrocenedicarboxylic acid gives a mixed-valence Sn4II-Sn4 IIIO4 cluster. The cubic tin-oxygen core is connected to six ferrocene units through twelve carboxylate bridges in such a way that the iron centers occupy the vertices of a regular octahedron (see structure: Fe Red; C gray; O green; Sn brown).

引用

页码：2409 / 2411

页数：3

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