Chlorobis(pentafluorophenyl)alane: synthesis, crystal structure, and polymerization catalysis

被引：31

作者：

Chakraborty, D ^{[1
]}

Chen, EYX ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 09期

关键词：

alane; organoalane; polymerization catalysis; catalyst;

D O I：

10.1016/S1387-7003(02)00539-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Al(C6F5)(3) with 0.34 equiv CH2Cl2 Cleanly produces chlorobis(pentafluorophenyl)alane (C6F5)(2)AlCl, the dimeric structure in the solid-state of which has been confirmed by X-ray diffraction studies. This chloroalane exhibits remarkable activity in polymerizations of styrene, epsilon-caprolactone, and cyclohexene oxide. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：698 / 701

页数：4

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